ADED FILTERO Write structure(s) for the major organic product(s) from the following reaction. Show both stereoisomers if needed. H₂O, H₂SO(cat.) CH3 OH + Edit Drawing eTextbook and Media OH CH3 13
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- For each compound, give the product(s) expected from (1) HgSO4>H2SO4@catalyzedhydration and (2) hydroboration–oxidation. cyclodecyneWrite equations for the reaction of 2-butanol with reagent. Where you predict no reaction, write NR. Q)K2Cr2O7, H2SO4, H2O, heatPredict the major products formed when 2- methyl-1-butene reacts with: H2, Pt/25°C. Show the reaction mechanism the given alkene reactions
- Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactionsCan you elaborate on how you determined how CH3CH2OH (part B) has a higher delta Hvap? Is this in relation to the london dispersion forces or the lewis diagram?
- (10pts) Compound A, C10H16, was found to be optically active. On catalytic reduction over a palladium catalyst, 2 equivalents of hydrogen were absorbed, yielding compound B, CioH2o. On ozonolysis of A, two fragments were obtained. One fragment was identified as acetic acid (CHCOOH). The other fragment, compound C, was an optically active carboxylic acid, C8H14O2. Write reactions, and draw the correct structures for A-C, explain your answer in detail.Drawing on what you know about the stereochemistry of alkene addition reactions, a. write the mechanism for the reaction of 2-butyne with one equivalent of Br2. b. predict the configuration of the product of the reaction.DHA is a fatty acid derived from sh oil and an abundant fatty acid in vertebrate brains. Hydrogenation of DHA forms docosanoic acid [CH3(CH2)20CO2H] and ozonolysis forms CH3CH2CHO, CH2(CHO)2 (ve equivalents), and HCOCH2CH2CO2H. What is the structure of DHA if all double bonds have the Z conguration?
- Predict the organic product(s) of the reaction of 2-butene with each reagent. Q.) Cl2 in H2ODrawing on what you know about the stereochemistry of alkene addition reactions, a. write the mechanism for the reaction of 2-butyne with one equivalent of Br2. A. predict the configuration of the product of the reaction.#B: Methyl acetate has methoxy, -OCH3 as the remaining of the alcohol part in the ester. Isopropyl acetate has isopropoxy, -OCH(CH3)2 as the remaining of the alcohol part in the ester. -OCH(CH3)2 is more electron donating than the methoxy, -OCH3 group due to the presence of two electron-donating -CH3 group in the former. Hence saponification reaction of Isopropyl acetate is much slower than methyl acetate. Hence the rate of saponification of methyl acetate, CH3CCO2CH3 is 50 times greater than that for isopropyl acetate.