AgCI(s) 2 Ag* (aq) + CIF (aq) Ksp = 4.0 x 10-0 Ag* (aq) + 2 CI (aq) 2 [AgCl] (aq) K2 = 1.8 x 105 AgCl(s) + CI (aq) 2 [AgCl,] (aq) K3 = ? () The student finds that AgCl is more soluble in NaCl(ag) than in water because of the series of reactions above. Determine the value of K3 for the overall reaction.

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter14: Chemical Equilibrium
Section: Chapter Questions
Problem 14.67QE
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AgCl(s) 2 Ag+ (aq) + CI- (aq) Ken = 4.0 x 10-10
ds.
Ag* (aq) + 2 CIF (aq) 2 [AgCl,] (aq)
K2 = 1.8 x 105
AgCl(s) + CIF (aq) [AgCl,]¯ (aq)
K3 = ?
(i) The student finds that AgCl is more soluble in NaCI(aq) than in water because of the series of reactions above. Determine the value of K3 for the overall reaction.
В I U
x2
X2 5
Ω
II
Transcribed Image Text:AgCl(s) 2 Ag+ (aq) + CI- (aq) Ken = 4.0 x 10-10 ds. Ag* (aq) + 2 CIF (aq) 2 [AgCl,] (aq) K2 = 1.8 x 105 AgCl(s) + CIF (aq) [AgCl,]¯ (aq) K3 = ? (i) The student finds that AgCl is more soluble in NaCI(aq) than in water because of the series of reactions above. Determine the value of K3 for the overall reaction. В I U x2 X2 5 Ω II
2 of 2
The student then conducts an experiment to determine the solubility of AgCl in a 2.5 M NaCl solution at various temperatures. Some AgCl(s) remains in the container at all temperatures studied. The
data are plotted on the graph below.
0.9
0.8
0.7
0.6
0.5-
0.4+
70
75
80
85
90
95 100
Temperature (°C)
(h) A 1000. g sample of a saturated solution at 95° C is cooled to 85°C. Determine the mass of AgCl(s) that would precipitate out of the solution.
B
U
x2
X.
Mass of AgCl Dissolved
solution)
Transcribed Image Text:2 of 2 The student then conducts an experiment to determine the solubility of AgCl in a 2.5 M NaCl solution at various temperatures. Some AgCl(s) remains in the container at all temperatures studied. The data are plotted on the graph below. 0.9 0.8 0.7 0.6 0.5- 0.4+ 70 75 80 85 90 95 100 Temperature (°C) (h) A 1000. g sample of a saturated solution at 95° C is cooled to 85°C. Determine the mass of AgCl(s) that would precipitate out of the solution. B U x2 X. Mass of AgCl Dissolved solution)
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