Alkoxides R-O- can be used to synthesize alkenes as exemplified by the reaction shov below, where the symbol (et) indicates that the substance is dissolved in ethanol (CH;CH,OH) used as solvent: Br (1) HO, Br(et) (et) (g) + + (et) CH,CH,OH + t-but-Br Ethoxide Isobutylene 10. What is the value of the rate constant for the synthesis of isobutylene at 25 °C? Initial Rate (M/s) [isobutylene] а) 6.8 х10-8 Trial Initial Initial [t-but-Br] [Ethoxide] b) 8.5 x10-7 6.8 x 10-8 13.6 x 10-8 1 0.08 M 0.04 M c) 2.1 x 10-5 0.16 M 0.04 M 6.8 x 10-8 13.6 x 10-8 d) 1.1 x10-5 3 0.08 M 0.08 M 4 0.16 M 0.08 M

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Chapter11: Chemical Kinetics
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Alkoxides R-O can be used to synthesize alkenes as exemplified by the reaction shov
below, where the symbol (et) indicates that the substance is dissolved in ethanol
(CH,CH,OH) used as solvent:
Br
+
(1)
Br(et)
(et)
+
(et)
CH,CH,OH
+
t-but-Br
Ethoxide
Isobutylene
10. What is the value of the rate constant for the synthesis of isobutylene at 25 °C?
а) 6.8 х10-8
Trial
Initial
Initial
Initial Rate (M/s)
[t-but-Br]
[Ethoxide]
[isobutylene]
b) 8.5 x10-7
6.8 x 10-8
13.6 х 10-8
1
0.08 M
0.04 M
c) 2.1 x 10-5
0.16 M
0.04 M
0.08 M
0.08 M
6.8 x 10-8
13.6 x 10-8
d) 1.1 x10-5
3
0.08 M
4
0.16 M
Transcribed Image Text:Alkoxides R-O can be used to synthesize alkenes as exemplified by the reaction shov below, where the symbol (et) indicates that the substance is dissolved in ethanol (CH,CH,OH) used as solvent: Br + (1) Br(et) (et) + (et) CH,CH,OH + t-but-Br Ethoxide Isobutylene 10. What is the value of the rate constant for the synthesis of isobutylene at 25 °C? а) 6.8 х10-8 Trial Initial Initial Initial Rate (M/s) [t-but-Br] [Ethoxide] [isobutylene] b) 8.5 x10-7 6.8 x 10-8 13.6 х 10-8 1 0.08 M 0.04 M c) 2.1 x 10-5 0.16 M 0.04 M 0.08 M 0.08 M 6.8 x 10-8 13.6 x 10-8 d) 1.1 x10-5 3 0.08 M 4 0.16 M
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