An analyst needs to evaluate the potential effect of an interferent, I, on the quantitative analysis for an analyte, A. She begins by measuring the signal for a sample in which the interferent is absent and the analyte is present with a concentration of 15 ppm, obtaining an average signal of 23.3 (arbitrary units). When analyzing a sample in which the analyte is absent and the interferent is present with a concentration of 25 ppm, she obtains an average signal of 13-7.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter6: Random Errors In Chemical Analysis
Section: Chapter Questions
Problem 6.17QAP
icon
Related questions
Question
An analyst needs to evaluate the potential effect
of an interferent, I, on the quantitative analysis
for an analyte, A. She begins by measuring the
signal for a sample in which the interferent is
absent and the analyte is present with a
concentration of 15 ppm, obtaining an average
signal of 23.3 (arbitrary units). When analyzing
a sample in which the analyte is absent and the
interferent is present with a concentration of 25
ppm, she obtains an average signal of 13.7.
Transcribed Image Text:An analyst needs to evaluate the potential effect of an interferent, I, on the quantitative analysis for an analyte, A. She begins by measuring the signal for a sample in which the interferent is absent and the analyte is present with a concentration of 15 ppm, obtaining an average signal of 23.3 (arbitrary units). When analyzing a sample in which the analyte is absent and the interferent is present with a concentration of 25 ppm, she obtains an average signal of 13.7.
Solve the following problems
a. What is the analyte's sensitivity?
b. What is the interferent's sensitivity?
c. What is the value of the selectivity coefficient?
d. Is the method more selective for the analyte or
the interferent?
e. What is the maximum concentration of
interferent relative to that of the analyte (i.e.,
[interferent]/[analyte]), if the error in the
analysis is to be less than 1%?
Transcribed Image Text:Solve the following problems a. What is the analyte's sensitivity? b. What is the interferent's sensitivity? c. What is the value of the selectivity coefficient? d. Is the method more selective for the analyte or the interferent? e. What is the maximum concentration of interferent relative to that of the analyte (i.e., [interferent]/[analyte]), if the error in the analysis is to be less than 1%?
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 4 steps

Blurred answer
Knowledge Booster
Spectroanalytical Methods
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Fundamentals Of Analytical Chemistry
Fundamentals Of Analytical Chemistry
Chemistry
ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Appl Of Ms Excel In Analytical Chemistry
Appl Of Ms Excel In Analytical Chemistry
Chemistry
ISBN:
9781285686691
Author:
Crouch
Publisher:
Cengage
EBK A SMALL SCALE APPROACH TO ORGANIC L
EBK A SMALL SCALE APPROACH TO ORGANIC L
Chemistry
ISBN:
9781305446021
Author:
Lampman
Publisher:
CENGAGE LEARNING - CONSIGNMENT