Using the absorbance of [FeSCN]+2 at the wavelength of maximum absorption which you obtained in part B, and the diameter of the tube, obtained in part A,calculate the molar extinction coefficient.

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter14: Rotational And Vibrational Spectroscopy
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Using the absorbance of [FeSCN]+2 at the wavelength of maximum absorption which you obtained in part B, and the diameter of the tube, obtained in part A,calculate the molar extinction coefficient.

given info:

Concentration of Fe3+ stock solution, C1 = 0.001 M

Volume of stock Fe3+ solution pipetted, V1 = 25mL

Concentration of diluted stock solution, C2 = 0.0004 M

Volume of Fe2+ solution and KSCN (upon mixing) = 10mL

Weight of KSCN = 1g

The reaction taking place is given as:

The reaction taking place is given as:

F

e

3+

 (aq) + SC

N

 (aq) ⇔Fe

[SCN]

2+

 (aq)

 

the concentration of [FeSCN]2+ after the  mixing of Fe3+ and SCN- is 2.5 x 10-3 M.

 

Moles of [FeSCN]2+ = 2.5 x 10-5 moles

Diameter:1.2cm

The wavelength at which maximum absorption takes place is 

= 480 nm

 

 

 

Spectral data :
Wavelength (nm)
A
.80
1.05
400
420
1.23
1,33
1.40
1.39
440
460
480
500
l,30
1.08
181
520
540
560
580
56
32
18
09
00
600
620
640
660
680
00
700
100 0
28 -5
Transcribed Image Text:Spectral data : Wavelength (nm) A .80 1.05 400 420 1.23 1,33 1.40 1.39 440 460 480 500 l,30 1.08 181 520 540 560 580 56 32 18 09 00 600 620 640 660 680 00 700 100 0 28 -5
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