An aqueous solution is prepared in which 0.00113 mol Ni(NO3)2 and 0.484  mol NH3 are dissolved in a total volume of 1.00 L. Kf for Ni(NH3)62+ is equal to 5.5 × 108. Write the expression for the dissociation constant needed to determine the concentration of Ni(H2O)62+ ions at equilibrium in the solution formed in Part 1.   Kd​ = [Ni2+][NH3​]^6/[Ni(NH3​)^2+ 6​]​   Calculate the concentration of Ni(H2O)62+ ions at equilibrium in the solution formed.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section12.3: Determining Equilibrium Constants
Problem 12.3PSP
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An aqueous solution is prepared in which 0.00113 mol Ni(NO3)2 and 0.484  mol NH3 are dissolved in a total volume of 1.00 L.
Kf for Ni(NH3)62+ is equal to 5.5 × 108.

Write the expression for the dissociation constant needed to determine the concentration of Ni(H2O)62+ ions at equilibrium in the solution formed in Part 1.

 
Kd​ = [Ni2+][NH3​]^6/[Ni(NH3​)^2+ 6​]​
 
Calculate the concentration of Ni(H2O)62+ ions at equilibrium in the solution formed.
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