762 CHAPTER 17 Additional Aspects of Aqueous Equilibria 17.55 A 1.00-L solution saturated at 25 °C with calcium oxalate (CaC2O4) contains 0.0061 g of CaC2O4. Calculate the solubility-product constant for this salt at 25 °C. 17.56 A 1.00-L solution saturated at 25 °C with lead(II) iodide contains 0.54 g of Pbl2. Calculate the solubility-product constant for this salt at 25 °C. 17.57 Using Appendix D, calculate the molar solubility of AgBr in (a) pure water, (b) 3.0 × 10 2 M AgNO3 solution, (c) 0.10 M NaBr solution. 17.58 Calculate the solubility of LaF3 in grams per liter in (a) pure water, (b) 0.010 M KF solution, (c) 0.050 M LaCl3 solution. 17.59 Consider a beaker containing a saturated solution of CaF, in equilibrium with undissolved CaF2(s). Solid CaCl, is then added to the solution. (a) Will the amount of solid CaF, at the bottom of the beaker increase, decrease, or re- main the same? (b) Will the concentration of Ca²+ ions in solution increase or decrease? (c) Will the concentration of F ions in solution increase or decrease? 7.60 Consider a beaker containing a saturated solution of PbI2 in equilibrium with undissolved PbI2(s). Now solid KI is added to this solution. (a) Will the amount of solid Pbl2 at the bottom of the beaker increase, decrease, or remain the same? (b) Will the concentration of Pb2+ ions in solution increase or decrease? (c) Will the concentration of I ions in solution increase or decrease? .61 Calculate the solubility of Mn(OH)2 in grams per liter when buffered at pH (a) 7.0, (b) 9.5, (c) 11.8. -62 Calculate the molar golul 'i

Principles of Modern Chemistry
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Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
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Chapter16: Solubility And Precipitation Equilibria
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762
CHAPTER 17 Additional Aspects of Aqueous Equilibria
17.55 A 1.00-L solution saturated at 25 °C with calcium oxalate
(CaC2O4) contains 0.0061 g of CaC2O4. Calculate the
solubility-product constant for this salt at 25 °C.
17.56 A 1.00-L solution saturated at 25 °C with lead(II) iodide
contains 0.54 g of Pbl2. Calculate the solubility-product
constant for this salt at 25 °C.
17.57 Using Appendix D, calculate the molar solubility of AgBr in
(a) pure water, (b) 3.0 × 10 2 M AgNO3 solution, (c) 0.10 M
NaBr solution.
17.58 Calculate the solubility of LaF3 in grams per liter in (a) pure
water, (b) 0.010 M KF solution, (c) 0.050 M LaCl3 solution.
17.59 Consider a beaker containing a saturated solution of CaF,
in equilibrium with undissolved CaF2(s). Solid CaCl, is
then added to the solution. (a) Will the amount of solid
CaF, at the bottom of the beaker increase, decrease, or re-
main the same? (b) Will the concentration of Ca²+ ions in
solution increase or decrease? (c) Will the concentration of
F ions in solution increase or decrease?
7.60 Consider a beaker containing a saturated solution of PbI2
in equilibrium with undissolved PbI2(s). Now solid KI is
added to this solution. (a) Will the amount of solid Pbl2 at
the bottom of the beaker increase, decrease, or remain the
same? (b) Will the concentration of Pb2+ ions in solution
increase or decrease? (c) Will the concentration of I ions
in solution increase or decrease?
.61 Calculate the solubility of Mn(OH)2 in grams per liter
when buffered at pH (a) 7.0, (b) 9.5, (c) 11.8.
-62 Calculate the molar golul 'i
Transcribed Image Text:762 CHAPTER 17 Additional Aspects of Aqueous Equilibria 17.55 A 1.00-L solution saturated at 25 °C with calcium oxalate (CaC2O4) contains 0.0061 g of CaC2O4. Calculate the solubility-product constant for this salt at 25 °C. 17.56 A 1.00-L solution saturated at 25 °C with lead(II) iodide contains 0.54 g of Pbl2. Calculate the solubility-product constant for this salt at 25 °C. 17.57 Using Appendix D, calculate the molar solubility of AgBr in (a) pure water, (b) 3.0 × 10 2 M AgNO3 solution, (c) 0.10 M NaBr solution. 17.58 Calculate the solubility of LaF3 in grams per liter in (a) pure water, (b) 0.010 M KF solution, (c) 0.050 M LaCl3 solution. 17.59 Consider a beaker containing a saturated solution of CaF, in equilibrium with undissolved CaF2(s). Solid CaCl, is then added to the solution. (a) Will the amount of solid CaF, at the bottom of the beaker increase, decrease, or re- main the same? (b) Will the concentration of Ca²+ ions in solution increase or decrease? (c) Will the concentration of F ions in solution increase or decrease? 7.60 Consider a beaker containing a saturated solution of PbI2 in equilibrium with undissolved PbI2(s). Now solid KI is added to this solution. (a) Will the amount of solid Pbl2 at the bottom of the beaker increase, decrease, or remain the same? (b) Will the concentration of Pb2+ ions in solution increase or decrease? (c) Will the concentration of I ions in solution increase or decrease? .61 Calculate the solubility of Mn(OH)2 in grams per liter when buffered at pH (a) 7.0, (b) 9.5, (c) 11.8. -62 Calculate the molar golul 'i
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