An electrolytic cell is constructed using platinum electrodes in an aqueous NaHCO3 solution. The electrolytic cell is attached to a 9V battery for 2.5 hours, producing 55 mL of H₂(g) at 1.00 atm and 298 K. 2HCO3(aq) + 2e → H₂(g) + 2CO3²-(aq) E° = -0.83 V O2(g) + 4CO2(g) + 2H2O(l) + 4e → 4HCO3- (aq) E° = 2.73 V a. Identify the anode reaction, cathode reaction, and cell reaction. Anode: Cathode: Cell: b. Calculate the current running through the cell. c. Calculate the total volume of gas produced during the electrolysis.

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Chapter19: The Chemistry Of The Main-group Elements
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An electrolytic cell is constructed using platinum electrodes in an aqueous NaHCO3 solution. The
electrolytic cell is attached to a 9V battery for 2.5 hours, producing 55 mL of H₂(g) at 1.00 atm and
298 K.
2HCO3(aq) + 2e- → H₂(g) + 2CO3²-(aq)
E° = -0.83 V
O2(g) + 4CO2(g) + 2H₂O(l) + 4e¯→ 4HCO3- (aq)
E° = 2.73 V
a. Identify the anode reaction, cathode reaction, and cell reaction.
Anode:
Cathode:
Cell:
b. Calculate the current running through the cell.
c. Calculate the total volume of gas produced during the electrolysis.
Transcribed Image Text:An electrolytic cell is constructed using platinum electrodes in an aqueous NaHCO3 solution. The electrolytic cell is attached to a 9V battery for 2.5 hours, producing 55 mL of H₂(g) at 1.00 atm and 298 K. 2HCO3(aq) + 2e- → H₂(g) + 2CO3²-(aq) E° = -0.83 V O2(g) + 4CO2(g) + 2H₂O(l) + 4e¯→ 4HCO3- (aq) E° = 2.73 V a. Identify the anode reaction, cathode reaction, and cell reaction. Anode: Cathode: Cell: b. Calculate the current running through the cell. c. Calculate the total volume of gas produced during the electrolysis.
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