An exothermic reaction is always spontaneous. Product formation is always favored in a reaction with a negative AH° and a negative A.S. A reaction will have an equilibrium constant that is greater than one if AG for the reaction is negative. Entropy decreases as the temperature increases. The entropy of a substance increases when a liquid vaporizes to a gas at any temperature. For an exothermic reaction, an increase in temperature results in a decrease in the equilibrium constant.
An exothermic reaction is always spontaneous. Product formation is always favored in a reaction with a negative AH° and a negative A.S. A reaction will have an equilibrium constant that is greater than one if AG for the reaction is negative. Entropy decreases as the temperature increases. The entropy of a substance increases when a liquid vaporizes to a gas at any temperature. For an exothermic reaction, an increase in temperature results in a decrease in the equilibrium constant.
Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
Section: Chapter Questions
Problem 68SCQ: Explain why each of the following statements is incorrect. (a) Entropy increases in all spontaneous...
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