Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 16, Problem 15E
Indicate which substance in the given pairs has the higher entropy value. Explain your choices..
(a) C2H5OH(l) or C3H7OH(l).
(b) C2H5OH(l) or C2H5OH(g).
(c) 2H(g) or H(g)
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Chemistry by OpenStax (2015-05-04)
Ch. 16 - What is a spontaneous reaction?Ch. 16 - What is a nonspontaneous reaction?Ch. 16 - Indicate whether the following processes are...Ch. 16 - A helium-filled balloon spontaneously deflates...Ch. 16 - Many plastic materials are organic polymers that...Ch. 16 - In Figure 16.8 all possible distributions and...Ch. 16 - In Figure 16.8 all of the possible distributions...Ch. 16 - How does the process described in the previous...Ch. 16 - Consider a system similar to the one in Figure...Ch. 16 - Consider the system shown in Figure 16.9. What is...
Ch. 16 - Consider the system shown in Figure 16.9. What is...Ch. 16 - Arrange the following sets of systems in order of...Ch. 16 - At room temperature, the entropy of the halogens...Ch. 16 - Consider two processes: sublimation of I2(s) and...Ch. 16 - Indicate which substance in the given pairs has...Ch. 16 - Predict the sign of the entropy change for the...Ch. 16 - Predict the sign of the entropy change for the...Ch. 16 - Write the balanced chemical equation for the...Ch. 16 - Write the balanced chemical equation for the...Ch. 16 - What is the difference between S, S , and S 298...Ch. 16 - Calculate S298 for the following changes. (a)...Ch. 16 - Determine the entropy change for the combustion of...Ch. 16 - Determine the entropy change for the combustion of...Ch. 16 - Thermite reactions have been used for welding...Ch. 16 - Using the relevant S 298 values listed in Appendix...Ch. 16 - From the following information, determine S298 for...Ch. 16 - By calculating Suniv, at each temperature,...Ch. 16 - Use the standard entropy data in Appendix G to...Ch. 16 - Use the standard entropy data in Appendix G to...Ch. 16 - What is the difference between G, G, and G 298 for...Ch. 16 - A reaction has H298=100 kj/mol and S298=250 J/mol ...Ch. 16 - Explain what happens as a reaction starts with G0...Ch. 16 - Use the standard free energy of formation data in...Ch. 16 - Use the standard free energy data in Appendix G to...Ch. 16 - Given: P4(s)+5O2(g)P4O10(s)G298=2697.0kJ/mol...Ch. 16 - Is the formation of ozone (O3(g)) from oxygen...Ch. 16 - Consider the decomposition of red mercury(II)...Ch. 16 - Among other things, an ideal fuel for the control...Ch. 16 - Calculate G for each of the following reactions...Ch. 16 - Calculate G for each of the following reactions...Ch. 16 - Calculate the equilibrium constant at 25 C for...Ch. 16 - Calculate the equilibrium constant at 25 C for...Ch. 16 - Calculate the equilibrium constant temperature...Ch. 16 - Calculate the equilibrium constant temperature...Ch. 16 - Consider the following reaction at 298 K:...Ch. 16 - Determine the normal boiling point (in kelvin) of...Ch. 16 - Under what conditions is N2O3(g)NO(g)+NO2(g)...Ch. 16 - At mom temperature, the equilibrium constant (Kw)...Ch. 16 - Hydrogen sulfide is a pollutant found in natural...Ch. 16 - Consider the decomposition of CaCO3(s) into CaO(s)...Ch. 16 - In the laboratory, hydrogen chloride (HCl(g)) and...Ch. 16 - Benzene can be prepared from acetylene....Ch. 16 - Carbon dioxide decomposes into CO and O2 at...Ch. 16 - Carbon tetrachloride, an important industrial...Ch. 16 - Acetic acid, CH3CO2H, can form a dimer,...Ch. 16 - Nitric acid, HNO3, can be prepared by the...Ch. 16 - Determine G for the following reactions. (a)...Ch. 16 - Given that the Gf for Pb2+(aq) and Cl-(aq) is...Ch. 16 - Determine the standard free energy change, Gf, for...Ch. 16 - Determine the standard enthalpy change, entropy...Ch. 16 - The evaporation of one mole of water at 298 K has...Ch. 16 - In glycolysis, the reaction of glucose (Glu) to...Ch. 16 - One of the important reactions in the biochemical...Ch. 16 - Without doing a numerical calculation, determine...Ch. 16 - When ammonium chloride is added to water and...Ch. 16 - An important source of copper is from the copper...Ch. 16 - What happens to G (becomes more negative or more...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What is entropy? Why is entropy important?arrow_forward10.104 (a) When a chemical bond forms, what happens to the entropy of the system? (b) Thermodynamically, what allows any bond formation to occur? (c) What do your answers to parts (a) and (b) suggest must be true about the formation of chemical bonds for the octet rule to hold?arrow_forwardIs the following reaction spontaneous as written? Explain. Do whatever calculation is needed to answer the question. CH4(g)+N2(g)HCN(g)+NH3(g)arrow_forward
- Many plastic materials are organic polymers that contain carbon and hydrogen. The oxidation of these plastics in air to farm carbon dioxide and water is a spontaneous process; however, plastic materials tend to persist in the environment. Explain.arrow_forwardAt room temperature, the entropy of the halogens increases from I2 to Br2 to Cl2. Explain.arrow_forwardSomeone once suggested that it is impossible to unscramble a scrambled egg. Describe an unscrambled and a scrambled egg in terms of the concept of entropy.arrow_forward
- For each pair of items, tell which has the higher entropy and explain why. (a) Item 1, a sample of solid CO2 at -78°C, or item 2, CO2 vapor at 0°C (b) Item I, solid sugar, or item 2, the same sugar dissolved in a cup of tea (c) Item 1, a 100-mL sample of pure water and a 100-mL sample of pure alcohol, or item 2, the same samples of water and alcohol after they have been poured together and stirredarrow_forwardWithout doing a calculation, predict whether the entropy change will be positive or negative when each of the following reactions occurs in the direction it is written. (a) CH3OH(l)+3/2O2(g)CO2(g)+2H2O(g) (b) Br2(l)+H2(g)2HBr(g) (c) Na(s)+l/2F2(g)NaF(s) (d)CO(g)+2H2(g)CH3OH(l) (e) 2NH3(g)N2(g)+3H2(g)arrow_forwardThe free energy change, G, for a process at constant temperature and pressure is related to Suniv and reflects the spontaneity of the process. How is G related to Suniv? When is a process spontaneous? Nonspontaneous? At equilibrium? G is a composite term composed of H, T, and S. What is the G equation? Give the four possible sign combinations for H and S. What temperatures are required for each sign combination to yield a spontaneous process? If G is positive, what does it say about the reverse process? How does the G = H TS equation reduce when at the melting-point temperature of a solid-to-liquid phase change or at the boiling-point temperature of a liquid-to-gas phase change? What is the sign of G for the solid-to-liquid phase change at temperatures above the freezing point? What is the sign of G for the liquid-to-gas phase change at temperatures below the boiling point?arrow_forward
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