A(NH3)3+ is a complex ion. A+(aq) + NH3(aq) ⇌ ANH3+(aq).                 K 1 = 3.3 x 10^3 ANH3+(aq) + NH3(aq) ⇌ A(NH3)2+(aq)      K2 = 6.4 x 10^3 A(NH3)2+(aq) + NH3(aq) ⇌ A(NH3)3+(aq) K3 = 1.2 x 10^3 Calculate the equilibrium concentrations of all species in solution, including the spectator ions, NH4+, OH−, and H+, if 100.0 mL of 0.100 M ANO3 is added to 300.0 mL of 2.0 M NH3.

Chemistry
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Author:Steven S. Zumdahl
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Chapter16: Solubility And Complex Ion Equilibria
Section: Chapter Questions
Problem 64E: In the presence of NH3, Cu2+ forms the complex ion Cu(NH3)42+. If the equilibrium concentrations of...
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A(NH3)3+ is a complex ion.

A+(aq) + NH3(aq) ⇌ ANH3+(aq).                 K 1 = 3.3 x 10^3

ANH3+(aq) + NH3(aq) ⇌ A(NH3)2+(aq)      K2 = 6.4 x 10^3

A(NH3)2+(aq) + NH3(aq) ⇌ A(NH3)3+(aq) K3 = 1.2 x 10^3

Calculate the equilibrium concentrations of all species in solution, including the spectator ions, NH4+, OH−, and H+, if 100.0 mL of 0.100 M ANO3 is added to 300.0 mL of 2.0 M NH3.

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