Answer the following questions: a) How much As (74.9216 g/mol) is in the sample? b) Calculate % w/w As₂O₃ (197.841 g/mol) of the sample

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter16: Applications Of Neutralization Titrations
Section: Chapter Questions
Problem 16.20QAP
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Answer the following questions:

a) How much As (74.9216 g/mol) is in the sample?

b) Calculate % w/w As₂O₃ (197.841 g/mol) of the sample 

11-12 The arsenic of a 2.000-g sample of a pesticide was converted to H;ASO4
by acid treatment. The excess acid was then neutralized, and 50.00 mL of
0.05871 M AgNO, was added to precipitate the arsenic quantitatively as
Ag-AsO4. The excess Agt in the filtrate and in the washings from the precipitate
was titrated with 10.21 mL of 0.1000 M KSCN.
3-
AsO4³(aq) + 3Ag+ (aq) → Ag3 AsO4(s)
Ag+ (aq)
+ SCN- (aq) → AgSCN(s)
Transcribed Image Text:11-12 The arsenic of a 2.000-g sample of a pesticide was converted to H;ASO4 by acid treatment. The excess acid was then neutralized, and 50.00 mL of 0.05871 M AgNO, was added to precipitate the arsenic quantitatively as Ag-AsO4. The excess Agt in the filtrate and in the washings from the precipitate was titrated with 10.21 mL of 0.1000 M KSCN. 3- AsO4³(aq) + 3Ag+ (aq) → Ag3 AsO4(s) Ag+ (aq) + SCN- (aq) → AgSCN(s)
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