Arrange the following carboxylic acid derivatives in the order ofdecreasing reactivity towards nucleophilic acyl substitution (mostreactive first).Lola Be-i-NOUS 1c-i-OCH(CH₂)₂CH- -OCHIIIIIIIVI, II, III, IVI, III, IV, IIII, IV, III, IO II, I, III, IVWhich of the following statements is not true:Esters derived from monocarboxylic acids and monohydroxy alcohols are colorlessand generally nonpolar.Saponification is the hydrolysis of an ester by a strong base.Hydrogen ions serve as a catalyst in the hydrolysis of an ester.SO3 is the anhydride form of H2SO3. The following reaction produces:CH3CH₂-C-OCH(CH3)2 + NaOHCH3COONa+ CH3CH(OH)CH3CH3CH2COONa + CH3CH(OH)CH3CH3CH2COONa+ CH3CH2CH2OHCH3CH₂COOH + CH3CHCH3ONaOption 4

Note-Dear student , the given question is 6 multiple question , hence I solved first question…

Arrange the following carboxylic acid derivatives in the order of decreasing reactivity towards nucleophilic acyl substitution (most reactive first). H₂C- -CH₂ H₂C-C-N(CH₂)2 H₂C- -OCH₂ (CH₂)₂CH- II O I, II, III, IV O I, III, IV, II O II, IV, III, I O II, I, III, IV IV OCH₂

Arrange the following carboxylic acid derivatives in the order of decreasing reactivity towards nucleophilic acyl substitution (most reactive first). H₂C- -CH₂ H₂C-C-N(CH₂)2 H₂C- -OCH₂ (CH₂)₂CH- II O I, II, III, IV O I, III, IV, II O II, IV, III, I O II, I, III, IV IV OCH₂

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter23: Carbonyl Condensation Reactions

Section23.SE: Something Extra

Problem 64AP

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Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

Arrange the following carboxylic acid derivatives in the order of
decreasing reactivity towards nucleophilic acyl substitution (most
reactive first).
Lola Be-i-NOUS 1c-i-OCH
(CH₂)₂CH- -OCH
I
II
III
IV
I, II, III, IV
I, III, IV, II
II, IV, III, I
O II, I, III, IV
Which of the following statements is not true:
Esters derived from monocarboxylic acids and monohydroxy alcohols are colorless
and generally nonpolar.
Saponification is the hydrolysis of an ester by a strong base.
Hydrogen ions serve as a catalyst in the hydrolysis of an ester.
SO3 is the anhydride form of H2SO3.

The following reaction produces:
CH3CH₂-C-OCH(CH3)2 + NaOH
CH3COONa+ CH3CH(OH)CH3
CH3CH2COONa + CH3CH(OH)CH3
CH3CH2COONa+ CH3CH2CH2OH
CH3CH₂COOH + CH3CHCH3
ONa
Option 4

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