At 25 °C, the equilibrium partial pressures for the reaction 2 A(g) + 4 B(g) =2C(g)+D(g) were found to be PA = 4.74 bar, PR = 5.52 bar, Pc = 4.94 bar, and P = 5.78 bar. What is the standard change in Gibbs free energy of this reaction at 25 °C? %3D
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- At 25 °C, the equilibrium partial pressures for the reaction 2A(g)+4B(g)↽−−⇀2C(g)+D(g) were found to be PA=5.86 bar, PB=5.73 bar, PC=4.88 bar, and PD=4.65 bar. What is the standard change in Gibbs free energy of this reaction at 25 °C? ΔGrxn°= kJ/mola) Describe in your own words the relationship between standard change in Gibbs free energy associated with a chemical process (∆?o) and an equilibrium constant, Keq. A ∆?o of –3.8 kJ/mol is associated with the equilibrium 2A+B⇌C+D. If A and B are initially present in 1M concentration, find the equilibrium concentrations of all species. You know this reaction to be spontaneous at all temperatures, what can you deduce about the signs of the changes in enthalpy and entropy associated with this process? Why?The standard enthalpy of combustion of liquid ethyl ethanoate (ethyl acetate, CH3COOC2H5) is −2231 kJ mol−1 at 298 K and its standard molar entropy is 259.4 J K−1 mol−1. Calculate the standard Gibbs energy of formation of the compound at 298 K.
- a. Calculate the standard Gibbs free energy change for the process of dissolution of benzene in water. b. Find the chemical potential of benzene solution standard state ΔfGo(C6H6,aq).Calculate the change in molar Gibbs energy of carbon dioxide (treated as a perfect gas) at 20 °c when its pressure is changed isothermally from 1.0 bar to (a) 3.0 bar. (b) 2. 7 x 10-4 atm, its partial pressure in dry air at sea level.Estimate the enthalpy of reaction h̄R for the dissociation process CO2 ⇌ CO + 1⁄2 O2 at 2200 K, using (a) enthalpy data and (b) KP data.
- Provide the formal definition of enthalpy and explain all symbols used in it. Explain how the change in enthalpy is related to certain thermodynamic property (other than Gibbs energy).Calculate (a) the standard reaction entropy and (b) the change in entropyof the surroundings (at 298 K) of the reaction N2(g) + 3 H2(g) → 2 NH3(g). (c) Hence calculate the standard Gibbs energy of the reaction.Suppose a certain small bird has a mass of 30 g. What is the minimum mass of glucose that it must consume to fly to a branch 10 m above the ground? The change in Gibbs energy that accompanies the oxidation of 1.0 mol C6H12O6(s) to carbon dioxide and water vapour at 25 °C is -2828 kJ.
- Calculate the change in the standard entropy of the system, ΔS°, for the synthesis of ammonia from N2(g) and H2(g) at 298 K:N2(g) + 3 H2(g)----->2 NH3(g)I really need help with the caluclation and finding the answer please A reaction in which compound X is converted into compound Z has a change in enthalpy of 30 kJ/mol and a change in entropy of 240 J/mol. At 25C, what would be the Gibbs free energy? Gibbs energy is kJ/molEstimate the change in the Gibbs energy of 1.0 dm3 of liquid octane when the pressure acting on it is increased from 1.0 atm to 100 atm. Given that the mass density of octane is 0.703 g cm−3, determine the change in the molar Gibbs energy.