At -8.64 °C the concentration equilibrium constant K = 7.7 for a certain reaction. Here are some facts about the reaction: -1 • The initial rate of the reaction is 5.3 mol·L¯¹·s¯¹. . If the reaction is run at constant pressure, 132. kJ/mol of heat are absorbed. • The constant pressure molar heat capacity C = 2.97 J'mol K¹. Yes. Using these facts, can you calculate K at 16. °C? x10 O No. If you said yes, then enter your answer at right. Round it to 2 significant digits. If you said no, can you at least decide whether Kat 16. °C will be bigger or smaller than K at -8.64 °C? C Yes, and K will be bigger. Yes, and K will be smaller. No.

At -8.64 °C the concentration equilibrium constant K = 7.7 for a certain reaction. Here are some facts about the reaction: -1 • The initial rate of the reaction is 5.3 mol·L¯¹·s¯¹. . If the reaction is run at constant pressure, 132. kJ/mol of heat are absorbed. • The constant pressure molar heat capacity C = 2.97 J'mol K¹. Yes. Using these facts, can you calculate K at 16. °C? x10 O No. If you said yes, then enter your answer at right. Round it to 2 significant digits. If you said no, can you at least decide whether Kat 16. °C will be bigger or smaller than K at -8.64 °C? C Yes, and K will be bigger. Yes, and K will be smaller. No.

Chemistry & Chemical Reactivity

9th Edition

ISBN:9781133949640

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy

Section: Chapter Questions

Problem 54GQ: A crucial reaction for the production of synthetic fuels is the production of H2 by the reaction of...

See similar textbooks

Similar questions

Consider the reaction CO(g)+H2O(g)CO2(g)+H2(g) Use the appropriate tables to calculate (a) G at 552C (b) K at 552C
If wet silver carbonate is dried in a stream of hot air. the air must have a certain concentration level of carbon dioxide to prevent silver carbonate from decomposing by the reaction Ag2CO3(s)Ag2O(s)+CO2(g) H for this reaction is 79.14 kJ/mol in the temperature range of 25 to 125C. Given that the partial pressure of carbon dioxide in equilibrium with pure solid silver carbonate is 6.23 103 torr at 25C, calculate the partial pressure of CO2 necessary to prevent decomposition ofAg2CO3 at 110C. (Hint: Manipulate the equation in Exercise 79.)
Hydrogen gas and iodine gas react to form hydrogen iodide. If 0.500 mol H2 and 1.00 mol I2 are placed in a closed 10.0-L vessel, what is the mole fraction of HI in the mixture when equilibrium is reached at 205C? Use data from Appendix C and any reasonable approximations to obtain K.
Consider the reaction H2(g)+Br2(g)2HBr(g) where H = 103.8 kJ/mol. In a particular experiment, equal moles of H2(g) at 1.00 atm and Br2(g) at 1.00 atm were mixed in a 1.00-L flask at 25C and allowed to reach equilibrium. Then the molecules of H2 at equilibrium were counted using a very sensitive technique, and 1.10 1013 molecules were found. For this reaction, calculate the values of K, G, and S.
Explain how the entropy of the universe increases when an aluminum metal can is made from aluminum ore. Thefirst step is to extract the ore, which is primarily a formof A12O3, from the ground. After it is purified by freeingit from oxides of silicon and iron, aluminum oxide ischanged to the metal by an input of electrical energy. 2Al2O3(s)electricalenergy4Al(s)+3O2(g)
Silver carbonate, Ag2CO3, is a light yellow compound that decomposes when heated to give silver oxide and carbon dioxide: Ag2CO3(s)Ag2O(s)+CO2(g) A researcher measured the partial pressure of carbon dioxide over a sample of silver carbonate at 220C and found that it was 1.37 atm. Calculate the partial pressure of carbon dioxide at 25C. The standard enthalpies of formation of silver carbonate and silver oxide at 25C are 505.9 kJ/mol and 31.05 kJ/mol, respectively. Make any reasonable assumptions in your calculations. State the assumptions that you make, and note why you think they are reasonable.
Consider the reaction NH4+(aq) H+(aq)+NH3(aq) Use G f for NH3(aq) at 25C=26.7 kJ/mol and the appropriate tables to calculate (a) G at 25C (b) Ka at 25C
For each reaction, an equilibrium constant at 298 K is given. Calculate G for each reaction. (a) Br2()+ H2(g)2HBr(g) KP = 4.4 1018 (b) H2O()H2O(g) KP = 3.17 102 (c) N2(g) +3H2(g)2NH3(g) Kc = 3.5 108
What determines Ssurr for a process? To calculate Ssurr at constant pressure and temperature, we use the following equation: Ssurr = H/T. Why does a minus sign appear in the equation, and why is Ssurr inversely proportional to temperature?
One reaction that occurs in human metabolism is For this reaction G= 14 kJ at 25c. a. Calculate K for this reaction at 25C. b. In a living cell this reaction is coupled with the hydrolysis of ATP. (See Exercise 75.) Calculate G and K at 25C for the following reaction: Glutamicacid(aq)+ATP(aq)+NH3(aq)Glutamine(aq)+ADP(aq)+H2PO4(aq)
Hf for iodine gas is 62.4 kJ/mol, and S° is 260.7 J/mol K. Calculate the equilibrium partial pressures of I2(g), H2(g), and HI(g) for the system 2HI(g)H2(g)+I2(g) at 500°C if the initial partial pressures are all 0.200 atm.
A process that is reactant-favored at equilibrium can never be spontaneous. This statement is (a) true (b) false