At room temperature when HI (aq) is added to potassium bisulfite, KHSO3(s), sulfur dioxide is formed and the reaction vessel becomes cold. HI (aq) + KHSO3(s)→ SO2(g) + H2O(l) + K+(aq) + I-(aq). A.)Once the process has reached equilibrium at room temperature, which of the following must be true? choose one....(ΔH<TΔS, ΔH=TΔS, ΔH>TΔS, or need more info). B.) Once the process has reached equilibrium at room temperature, which of the following must be true? choose one....(ΔSuniv<0, ΔSuniv=0, ΔSuniv>0, or need more info).
At room temperature when HI (aq) is added to potassium bisulfite, KHSO3(s), sulfur dioxide is formed and the reaction vessel becomes cold. HI (aq) + KHSO3(s)→ SO2(g) + H2O(l) + K+(aq) + I-(aq). A.)Once the process has reached equilibrium at room temperature, which of the following must be true? choose one....(ΔH<TΔS, ΔH=TΔS, ΔH>TΔS, or need more info). B.) Once the process has reached equilibrium at room temperature, which of the following must be true? choose one....(ΔSuniv<0, ΔSuniv=0, ΔSuniv>0, or need more info).
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter12: Chemical Equilibrium
Section: Chapter Questions
Problem 51QRT: At room temperature, the equilibrium constant Kc for the reaction
2 NO(g) ⇌ N2(g) + O2(g)
is 1.4 ×...
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At room temperature when HI (aq) is added to potassium bisulfite, KHSO3(s), sulfur dioxide is formed and the reaction vessel becomes cold. HI (aq) + KHSO3(s)→ SO2(g) + H2O(l) + K+(aq) + I-(aq).
A.)Once the process has reached equilibrium at room temperature, which of the following must be true? choose one....(ΔH<TΔS, ΔH=TΔS, ΔH>TΔS, or need more info).
B.) Once the process has reached equilibrium at room temperature, which of the following must be true? choose one....(ΔSuniv<0, ΔSuniv=0, ΔSuniv>0, or need more info).
Expert Solution
Step 1
(A)
The system is at equilibrium means the free energy change of the system is equal to zero. Hence, the relation between enthalpy and entropy change can be obtained as,
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