(b) Decompose the representation below into the irreducible representations of C3v. 2C3 1 C3v T E 30v 1 (c) With the use of diagrams, find the representation of the C₂ point group to which a day orbital belongs.
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- Show that any irreducible representation of these point groups is normalized. a C2 b D2d c Oh d C4h e C6vWhat are the number of classes and the order of the following point groups? a C2v b D2h c D6h d S4 e Cs.Why is it unnecessary to consider whether an irreducible representation from C4h is orthogonal to an irreducible representation of D6h?
- Write a Slater determinant for the lithide ion, Li.Construct the symmetry-adapted linear combination molecular orbitals for hydrogen sulfide, H2S.Identify the symmetry elements present in the following objects. a The Eiffel Tower. You may have to look up a picture of it if you dont remember its shape b Any book ignore the printing. c An octagonal wood block. d A jack from the set of jacks pictured here: Note that some of the points end differently.
- Show that the irreducible representations of the D2d point group satisfy the closure requirement. You will have to use the great orthogonality theorem to reduce one combination.For the point group D3h, confirm that the irreducible representation E′ is orthogonal (in the sense defined by eqn 10B.7) to the irreducible representations A′1, A′2 , and E″.Identify the irreducible representations to which all five d orbitals of the central Xe atom in XeF4 (D4h) belong. Give reasons to support your answer ( please answer in detail )
- Identify the point groups to which the following objects belong: (i) a sphere, (ii) an isosceles triangle, (iii) an equilateral triangle, (iv) an unsharpened cylindrical pencil.a )Find the representation of the C2v point group to which a px orbital belongs. b)The four symmetry-adapted linear combinations (SALCs) built from the Cl 3s orbitals in the square planar (D4h) [PtCl4]2– anion have symmetry A1g, B1g, and Eu. List all expected Pt – SALC orbital combinations. and What information does the extended 1D2 term symbol provide about a given atom?What do you expect the structure of Ge2H4 to look like ? sketch the structure in a clear three dimensional representation and give it's point group.