Answered: b) Given (Ni(CN).F as a complex ion.…

b) Given (Ni(CN).F as a complex ion. Answer the questions below based on Valence Bond Theory. i) Predict its hybridization. i) State the magnetic properties and the type of spin.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes

Section: Chapter Questions

Problem 45P

See similar textbooks

Related questions

Q: Consider the complex square planar complex NiL4, where Ni2+ (d) is the central ion. Draw the system…

A: Solutions Given that Consider the complex square planer complex.. .…

Q: The oxalate ligand, [C:O4]²*, is a bidentate ligand and the structure of a complex ion [Fe(ox);]² is…

A: The given complex ion is a coordination complex with central metal ion (Fe3+) having 6-coordinate…

Q: Draw the molecular orbital diagram of the -complex ion [Fe(H2O)6]2+, also arrange the electronic…

A: [Fe(H2O)6]2+ consists of 6 H2O ligands and an oxidation state of +2 which means Fe consists of 6…

Q: Assign point groups to the two coordination complexes shown below. Give your reasoning/explanation…

A: In order to find the point group we have to follow the flowchart. Finding out the highest rotational…

Q: xplain the complexes below using Ligand Field Theory 1. [RhCl3(OH)3]3- 2. [Cr(en)2(PMe3)2]

A: The electrostatic crystal field theory and the molecular orbital theory were combined into a more…

Q: How do the relative magnitudes of Epairingand Δ affect theparamagnetism of a complex?

Q: e) Calculate the spin multiplicity of a metal ion Cr* assuming a high spin crystal field.

A: To calculate the spin multiplicity of Cr3+ metal ion

Q: Draw a molecular orbital diagram to show that CH3 molecule is a ơ-donor ligand.

Q: MeO2C. .CO2M. `N' Mn 'N' .N. MeO2C CO2Me CO2ME

Q: By using valence bond theory and ligand field theory, prove [Fe(acac)3] is a paramagnetic high spin…

Q: According to valence bond theory, what set of orbitals isused by a Period 4 metal ion in forming (a)…

A: a.

Q: What determine whether a molecule or ion complex is chiral? How would you differentiate between…

A: A chiral is an object that is not identically super-imposable with a mirror image of itself. An…

Q: 2. Octahedral complex are shown as below. OCH3 H3CO LOCH3 Al H3CO `OCH3 ÓCH3 a. Calculate the CFSE…

Q: Draw a diagram of the energy levels of the molecular orbitals of the complex [Ni (NH3) 6] 2+,…

A: Crystal field splitting energy in case of octahedral complexes: Before approaching ligands to the…

Q: Predict the geometry and number of unpaired spins in thefollowing four-coordinate complexes:…

A: [AuBr4]- Given information says that it is a 4-coordinate, hence it can be either square planar or…

Q: Calculate the electron in the following complexes. a,b,c,d

A: We have given that Calculate the electron in the given complexes.

Q: Given this complex [Co(NH3)Cl(en)2]Cl2 1. What is its systematic name 2. Write down it's…

Q: How many stereoisomers exist for octahedrally shaped complex MA4(en), assuming A is monodentate…

Q: The electronic arrangement of the complex ion in the attached picture according to the molecular…

Q: Calculate the Ligand-field stabilization energies (LFSE) for octahedral compounds which contain the…

A: The high spin complexes contain the unpaired electrons whereas the low spin complexes contain the…

Q: 2. Determine which of the following four coordinate complexes are tetrahedral and which are square…

A: There are number of theories have been proposed to determine the structure, magnetic behaviours of…

Q: Draw a molecular orbital diagram to show that CH3¯ molecule is a -donor ligand.

A: A molecular orbital diagram, or MO diagram, is a qualitative descriptive tool explaining chemical…

Q: By taking into account the following complexes: A) [Co(en):]³* B)[CoCl3Br3]+ a) Give the oxidation…

A: In this question, we have to find out the correct answer of given problem by the help of the…

Q: CI..... Cu ***...- Cl Consider the square base pyramidal [CuCls] complex. Using the provided…

A: To determine the reducible representation of any molecule belongs to a point we have to use the…

Q: CFT is applicable to molecules in geometries other than octahedral. In octahedral complexes,…

A: Crystal field theory considers the bond between metal and ligands to be ionic arising purely from…

Q: A3- Draw all the possible geometrical isomers for the complex [Cr(en)2(CN)2]. And show how could you…

A: Here we are required to find the geometrical isomer for the given complex.

Q: Classify the stereoisomerism and structural isomerism of coordination compounds. Give three examples…

A: Answers are explained below. Stereoisomerism of coordination compound is as follows :

Q: Why can the NH3 molecule serve as a ligand but the BH3 molecule cannot?

A: A ligand is an atom or group of atoms which is linked to a central metal atom or ion in a complex…

Q: CFSE and total spin moment

Q: li Calculate the magnetic moment for a complex of Ho3,

Q: Find SALCs and construct the MO diagram for a transition metal complex with octahedral symmetry.

Q: "Ligand field theory provides a basis for explaining the chemical behaviour of octahedral transition…

A: Ligand field theory was put forward by Hund and Mulliken. According to this theory, all the atomic…

Q: The two egorbitals are identical in energy in an octahedralcomplex but have different energies in a…

A: The ligands are electron donors and they can donate the unshared electron pairs to the electrophilic…

Q: D. Consider the reaction of RuClz with terpyridine ligand. I. a. Draw the complex ion structure when…

A: Given RuCl3 with terpyridine ligand Complex structure = to be determined Stereoisomer in complex =…

Q: (a) Using Werner’s definition of valence, which property isthe same as oxidation number, primary…

A: The coordination complexes can be defined as the complex compounds which have coordinate linkage…

Q: Visualizing Conplex. Tons construct [cr(H2O),], [cr CH2O)s S]* , [CrC HzO)yC1]*, and [Cocend2 C H2…

A: The compounds in which ligands are bonded to central metal atom, usually a transition metal, are…

Q: or the square planar complex(es) (NH3)2PtCl2, which best possibilities? 2, Wh a. Two isomers exist,…

A: Given that (NH3)2PtCl2 is a square planar complex and it does exits in two isomers- Cis and Trans.

Q: Write the examples of Bidentate and Polydentate ligands? Also distinguish them.

A: Ligands can be described as an anions or cations or neutral molecules which is further classified as…

Q: Answer the following questions for a square planar complex that has a dº metal center. a) What is…

A: The crystal field stabilization energy can be calculated as: CFSE=4(-0.51∆∘)+2(-0.43∆∘)+2(+0.23∆∘)+P…

Q: According to the theory of molecular orbitals, how are ligands classified and what effect do they…

A: On the basis of molecular orbital Theory , ligands are classified into : 1.) Only sigma donor 2.)…

Q: iv. Compound 2 has a distorted octahedral geometry, with four short and two longer Co-P bond…

A: The Phosphine ligand is a strong field ligand than "en" ligand because in phosphine ligand contains…

Q: Which is correct and which is incorrect from the following sentences? In any case, give a brief…

A: Here we have to predict the true or false statement from the following given statements.

Q: Is optical isomerism applicable for the complex? If yes, draw the enantiomeric pair.

Q: What are the characteristics of outer orbital complexes for octahedral complexes 1_hybridization is…

A: When the inner d orbital is used for hybridization then it is inner orbital complex . But when it is…

Q: prove that [Ru(OMe)2(PMe3)4] is a paramagnetic high spin octahedral complex using valence bond…

A: According to valancy bond theory we can say that about the hybridisation of the complexes.…

Q: Predict the geometry and number of unpaired spins inthe following four-coordinate complexes:…

A: Co-ordination compounds: These are the chemical compound formed by donation of electron or charges…

Q: Draw a diagram of the energy levels of the molecular orbitals of the complex [Ni(NH3)6]2+ , showing…

A: Solution The crystal theory fails to elucidate several physical properties of the transition metal…

Concept explainers

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.

Question

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Step by step

Solved in 2 steps with 1 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

1. Co(NH3)63+ is a low-spin complex while CoF63- is a high-spin complex. Give a rational for this difference by applying valence bond theory (i.e. illustration the hybridization and filling up of the metal orbitals). Which is the inner orbital complex and the outer orbital complex?
Which of the shown complexes are chiral (Figure 1)?
(a) Using Werner’s definition of valence, which property isthe same as oxidation number, primary valence or secondaryvalence? (b) What term do we normally use for the othertype of valence? (c) Why can NH3 serve as a ligand but BH3cannot?
Calculate the CFSE of the complex. (State how to search charge ligand Fe) Determine the hybridization of the metal central in the complex. (State the reason) Calculate the spin-only magnetic moment of the metal central in the complex. (State unpaired electron)
Will you explain why the total charge of this complex become -4? Do we not count the charge of Ca? and how do I know what charge Fe is since Fe charge can vary....
what is the CFSE and total spin moment of this complex
Predict the geometry and number of unpaired spins in thefollowing four-coordinate complexes: [AuBr4]-, [NiBr4]2-.Explain your reasoning.
By using valence bond theory and ligand field theory, prove [Fe(acac)3] is aparamagnetic high spin octahedral complex. (acac = acetylacetonato). Give the explaination.
Why can NH3 serve as a ligand but BH3 cannot?
What electronic feature must a donor atom of a ligand have?
Work out the stoichiometries and structures of the neutral complexes, chromium carbonyl, rhenium carbonyl, and nickel carbonyl using the 18-electron rule. Then use valence bond theory to determine the hybridizations of the orbitals in each complex?
Is the reason for k3 falling so much because en is a bulky ligand?