(b) The condensation reaction of acetone (CH3)2CO in aqueous solution is catalysed by base B, which reacts reversibly with acetone to form the carbion, C3H50¯. The carbion then reacts with a molecule of acetone to give product P АН + В BH + k1 A НА P k2 AH = acetone A = carbion B= base catalyst (i) Use steady state approximation to determine the concentration of the carbion and hence

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Chapter22: Surfaces
Section: Chapter Questions
Problem 22.44E: Are the following processes examples of homogeneous or heterogeneous catalysis? a Hydrolysis of...
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(b)
The condensation reaction of acetone (CH3)2CO in aqueous solution is catalysed by base B, which
reacts reversibly with acetone to form the carbion, C3H50¯. The carbion then reacts with a molecule of
acetone to give product P
АН
BH
A
k.1
A
НА
P
k2
AH = acetone A= carbion
B= base catalyst
(i)
Use steady state approximation to determine the concentration of the carbion and hence
derive the rate equation for the formation of product, P.
Transcribed Image Text:(b) The condensation reaction of acetone (CH3)2CO in aqueous solution is catalysed by base B, which reacts reversibly with acetone to form the carbion, C3H50¯. The carbion then reacts with a molecule of acetone to give product P АН BH A k.1 A НА P k2 AH = acetone A= carbion B= base catalyst (i) Use steady state approximation to determine the concentration of the carbion and hence derive the rate equation for the formation of product, P.
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