Balance the following reaction. If a reactant or product is not present, put a zero (0) in the blank.  H+(aq) +  H2O(l) +  ClO-13(aq) +  e-1 <-->  Cl-1(g) +  H+(aq) +  H2O(l)

Chemistry & Chemical Reactivity
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Chapter3: Chemical Reactions
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Problem 2PS: Write an equation from the following description: reactants are gaseous NH3 and O2, products are...
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Balance the following reaction. If a reactant or product is not present, put a zero (0) in the blank.

 H+(aq) +  H2O(l) +  ClO-13(aq) +  e-1 <-->  Cl-1(g) +  H+(aq) +  H2O(l)

Expert Solution
Step 1

ClO3- (aq ) ---------> Cl-1 (aq)

Oxidation state of Chlorine decreases from +5 (ClO3- ) to -1 ( Cl-1 ). So it is a reduction half reation.

 

Step 2

Since there are three O atom on left hand side, add 3 H2O molecules to the right hand side.

ClO3- (aq ) ---------> Cl-1 (aq) + 3H2O (l)

Now since there are 6 H atom on right hand side, add 6 H+ on left hand side

ClO3- (aq ) +6 H+ (aq) ---------> Cl-1 (aq) + 3H2O (l)

Now balance the charge. 

Left hand side =+ 5

Right hand side = -1

So add 5 electron to left-hand side

ClO3- (aq ) +6 H+ (aq) +5e- ---------> Cl-1 (aq) + 3H2O (l)

 

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