Base: Sodium Acetate pka: 4.76 *pH value for conjugate acid (Acetic Acid) Soln. #1 Weak Base Strong Acid H20 concentration (M) 0.500 0.250 n/a volume (mL) 50.0 50.0 0.0 * total volume is 100.0 mL [B'] : [HB] : pH: *pH = pKa + log([B-/[HB]) Soln. #2 Weak Base Strong Acid H20 concentration (M) 0.500 0.250 n/a volume (mL) 50.0 35.0 15.0 * total volume is 100.0 mL [B] : [HB] : pH: *pH = pKa + log([B-] / [HB]) Soln. #3 Weak Base Strong Acid H20 concentration (M) 0.500 0.250 n/a volume (mL) 50.0 25.0 25.0 * total volume is 100.0 mL [B'] : [HB] : pH: *pH = pKa + log([B-] / [HB])

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter14: Principles Of Neutralization Titrations
Section: Chapter Questions
Problem 14.32QAP
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1
Base:
Sodium Acetate
pKa:
4.76
*pH value for conjugate acid (Acetic Acid)
Soln. #1
Weak Base Strong Acid
H20
concentration (M)
volume (mL)
0.500
0.250
n/a
50.0
50.0
0.0
* total volume is 100.0 ml
[B']:
[HB] :
pH:
*pH = pka + log([B-] / [HB])
Soln. #2
Weak Base Strong Acid
H20
concentration (M)
0.500
0.250
n/a
volume (mL)
50.0
35.0
15.0
* total volume is 100.0 mL
[B]:
[HB] :
pH:
"pH = pKa + log([B-] / [HB])
Soln. #3
Weak Base Strong Acid
H20
concentration (M)
0.500
0.250
n/a
volume (mL)
50.0
25.0
25.0
total volume is 100.0 mL
[B'] :
[HB] :
pH:
*pH = pKa + log([B-]/ [HB])
Transcribed Image Text:Base: Sodium Acetate pKa: 4.76 *pH value for conjugate acid (Acetic Acid) Soln. #1 Weak Base Strong Acid H20 concentration (M) volume (mL) 0.500 0.250 n/a 50.0 50.0 0.0 * total volume is 100.0 ml [B']: [HB] : pH: *pH = pka + log([B-] / [HB]) Soln. #2 Weak Base Strong Acid H20 concentration (M) 0.500 0.250 n/a volume (mL) 50.0 35.0 15.0 * total volume is 100.0 mL [B]: [HB] : pH: "pH = pKa + log([B-] / [HB]) Soln. #3 Weak Base Strong Acid H20 concentration (M) 0.500 0.250 n/a volume (mL) 50.0 25.0 25.0 total volume is 100.0 mL [B'] : [HB] : pH: *pH = pKa + log([B-]/ [HB])
Base:
dium Acetate
pka:
*pH value for conjugate acid (Acetic Acid)
Soln. #1
Soln. #2
mL NaOH (0.100 м)
pH
mt NaOH (0.100 м)
pH
[B]:
[HB]:
[B]/ [HB] :
ml required to change pH:
[B]
[HB):
(B']/ [HB]:
ml required to change pH :
4.75
5.02
1
4.78
1
5.05
2
4.81
5.09
mol NaOH required:
mol NaOH required:
3
4.84
3
5.12
4
4.87
4
5.15
5
4.89
5
5.19
6.
4.92
6
5.22
7
4.95
7
5.26
8
4.98
5.30
5.01
9
5.34
10
5.04
10
5.38
11
5.07
11
5.43
12
5.11
12
5.48
13
5.17
13
5.54
14
5.21
14
5.60
15
16
17
5.25
15
5.66
5.28
16
5.74
5.32
17
5.83
18
5.37
18
5.93
19
5.41
19
6.07
20
5.46
20
6.26
21
5.51
22
5.57
23
5.64
24
5.71
25
5.79
26
5.89
27
6.02
28
6.18
29
6.44
30
7.15
Transcribed Image Text:Base: dium Acetate pka: *pH value for conjugate acid (Acetic Acid) Soln. #1 Soln. #2 mL NaOH (0.100 м) pH mt NaOH (0.100 м) pH [B]: [HB]: [B]/ [HB] : ml required to change pH: [B] [HB): (B']/ [HB]: ml required to change pH : 4.75 5.02 1 4.78 1 5.05 2 4.81 5.09 mol NaOH required: mol NaOH required: 3 4.84 3 5.12 4 4.87 4 5.15 5 4.89 5 5.19 6. 4.92 6 5.22 7 4.95 7 5.26 8 4.98 5.30 5.01 9 5.34 10 5.04 10 5.38 11 5.07 11 5.43 12 5.11 12 5.48 13 5.17 13 5.54 14 5.21 14 5.60 15 16 17 5.25 15 5.66 5.28 16 5.74 5.32 17 5.83 18 5.37 18 5.93 19 5.41 19 6.07 20 5.46 20 6.26 21 5.51 22 5.57 23 5.64 24 5.71 25 5.79 26 5.89 27 6.02 28 6.18 29 6.44 30 7.15
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ISBN:
9781285640686
Author:
Skoog
Publisher:
Cengage