Br, a) CH,CI, b) Br2 CH,Cl, c) Br2 CH,Cl,

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter9: Alkynes: An Introduction To Organic Synthesis
Section9.SE: Something Extra
Problem 49AP: Occasionally, a chemist might need to invert the stereochemistry of an alkene—that is, to convert...
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1.
Complete the following equations (assuming that the reactions occur via a bromonium ion). There
is no need to write the mechanism. If the reaction produces a pair of enantiomers, draw both
structures and assign the stereochemistry (R or S). If the reaction produces a meso compound,
you should assign its stereochemistry (R or S), but do not show its enantiomer, since it does not
represent a new compound. Clearly label any meso compounds.
Note that CH2CI2 is the solvent, not a reactant.
Br2
a)
CH,Cl,
Br2
(b)
CH,CI,
Brz
CH,CI,
Page 17 of 19
Transcribed Image Text:1. Complete the following equations (assuming that the reactions occur via a bromonium ion). There is no need to write the mechanism. If the reaction produces a pair of enantiomers, draw both structures and assign the stereochemistry (R or S). If the reaction produces a meso compound, you should assign its stereochemistry (R or S), but do not show its enantiomer, since it does not represent a new compound. Clearly label any meso compounds. Note that CH2CI2 is the solvent, not a reactant. Br2 a) CH,Cl, Br2 (b) CH,CI, Brz CH,CI, Page 17 of 19
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