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- A mixture of A, B, and C was added to a separatory funnel containing CH2Cl2and 10% aqueous NaOH solution. Which compound(s) are present in theaqueous layer, and which compound(s) are present in the organic layer?What are the nonprotein nitrogen components of the blood. Give their chemical structures and relative physiologic concentrations and describe their biosynthesis and excretion. Kindy insert your references. Thank you!Polyunsaturated fatty acids (PUFA's) in oils 0.g. sunflower oil are prone to rancidity because they contain conjugated double bond systems which are easily oxidized in the presence of light or peroxides. BHT Is used as an antioxidant in oils to prevent oxidative rancidity. How do BHT prevent oils from reacting with peroxides so that they do not become rancid? Show the mechanism.
- Repeated laboratory results over the past three weeks suggest that your patient suffers from acidemia. In the most recent visit, blood tests yielded the following results (normal values in parenthesis): pH = 7.34 (7.4) pCO2 = 60 mm Hg (40 mm Hg) [HCO3-] = 31 mM (24 mM) The problem is most likely due to: A) high glucose level in blood B) vomiting and nasogastric suction C) chronic respiratory center depression and central hypoventilation D) diabetic ketoacidosis E) none of the aboveCarbonic anhydrase of erythrocytes (?r 30,00030,000) has one of the highest turnover numbers known. It catalyzes the reversible hydration of CO2.CO2. H2O+CO2↽−−⇀H2CO3H2O+CO2↽−−⇀H2CO3 This is an important process in the transport of CO2CO2 from the tissues to the lungs. If 33 ?g of pure carbonic anhydrase catalyzes the hydration of 0.10 g0.10 g of CO2CO2 in 1 min1 min at 37 °C37 °C at ?max, what is the turnover number (?cat) of carbonic anhydrase? Please provide only typed answer solution no handwritten solution needed allowedCarbonic anhydrase is one of the fastest enzymes known. If 10 µg of this enzyme catalyzes the conversion of 0.30 g of CO2 to bicarbonate in 1 minute at 37˚C. What is the Kcat value for this enzyme in min -1?
- Q5: If the Ksp of Ca3N2 is 6.06 x 10-3, how many moles of calcium nitride (s) could you dissolve in 1.589 L of solvent (assume that calcium nitride (s) dissolves in water to form Ca2+(aq) and N3- (aq))? Enter your answer with at least 3 sig figs. Please provide only typed answer solution no handwritten solution needed allowedIsoleucine, another of the twenty amino acids found in proteins, is metabolized by a pathway that includes the following step. Propose a mechanism.During exercise when the body lacks an adequate supply of oxygen to support energy production, the pyruvate that is produced from the breakdown of glucose is converted into lactate. High lactate levels can lead to acidity in the muscle cells as some of the lactate hydrolyzes to lactic acid. The dissociation of lactic acid to lactate is shown in the reaction. Lactic acid has a p?apKa of 3.86.3.86. A solution containing a mixture of lactic acid and lactate was found to have a pH of 3.24.3.24. Calculate the ratio of the lactate concentration to the lactic acid concentration in this solution.
- The Ksp for AG2SO4 is 1.2x10^-5 and the Ksp for CaSO4 is 4.93x10^-5. How do I find the Ca concentration?When some sugars dissolve in water they spontaneously undergo changes in optical rotation called mutarrotation. The Mutarrotation of D-glucopyranose is catalyzed by acid and bases. 2-Hydroxypyridine is a more effective catalyst than phenol and pyridine for this reaction because: a.Both oxygen and N in 2-hydroxypyridine act as bases increasing the rapid interconversion of sugar b. The OH of 2-hydroxypyridine serves as the base while the current N as the acid. c. 2-hydroxypyridine acts both as a base to remove the proton from the hydroxyl group in the hemiacetal and as an acid to provide a proton to the oxygen in the hemiacetal. d.Phenol and pyridine are very expensive.d-Glucuronic acid is found widely in plants and animals. One of its functions is to detoxify poisonous HO-containing compoundsby reacting with them in the liver to form glucuronides. Glucuronides are water soluble and therefore readily excreted. Afteringestion of a poison such as turpentine or phenol, the glucuronides of these compounds are found in the urine. Draw thestructure of the a- and b-glucuronides formed by the reaction of b-d-glucuronic acid and phenol.
