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- provide the mechasim using the reagents shown ( asap)Explain the following result. Acetic acid (CH3COOH), labeled at its OH oxygen with theuncommon 18O isotope (shown in red), was treated with aqueous base, and then the solution was acidified. Two products having the 18O label at different locations were formed.Explain the following result. Acetic acid (CH3COOH), labeled at its OH oxygen with theuncommon 18O isotope (shown in red), was treated with aqueous base, and then the solution was acidied. Two products having the 18O label at different locations were formed.
- Draw a mechanism of the reduction of 188Re-perrhenate (Re(VII)) to Re(V) by using SnCl2.Identify the organic functional groups and reaction type for the following reaction.The reactant is a(n)a. beta pyranoseb. beta furanosec. alpha pyranosed. alpha furanoseThe product is a(n)a. alpha furanoseb. alpha pyranosec. beta furanosed. beta pyranoseThe reaction type is:a. oxidation (benedict's)b. esterificationc. mutarotationd. reduction (hydrogenation)e. hemiacetal formationTreatment with NaBH 4 converts aldose U into an optically inactive (meso) alditol V. Ruff degradation ofU gives W, whose alditol is optically inactive. Ruff degradation of W forms D-glyceraldehyde, thesimplest aldose. Upon Kiliani-Fischer synthesis, U is converted to two aldoses, X and Y. X is oxidized toan optically active aldaric acid Z. Y is oxidized to an optically inactive aldaric acid. Draw the structuresof D-glyceraldehyde, V, W, X, Y, and Z. Structure of compound U is shown below.
- PLZ GIVEN MECHASIM IN DETAILAn oligosaccharide isolated from an organism is found tocontain two glucose residues and one galactose residue.Exhaustive methylation followed by hydrolysis producedtwo glucoses with methoxy groups at positions 2, 3,and 6 and galactose with methoxy groups at positions2, 3, 4, and 6. What is the structure of the originaloligosaccharide?The attached isomerization reaction, drawn using D-glucose as startingmaterial, occurs with all aldohexoses in the presence of base. Draw astepwise mechanism that illustrates how each compound is formed.
- An aldopentose "O", is oxidized with HNO3 to a diacid "P" which is optically active. The compound "O", is also degraded to an aldotetrose "Q" which undergoes another oxidation to an optically inactive diacid "R". Assuming that "O" has the configuration D-(4R); what are the structures of "O" to "R"?Explain this result: Acetic acid (CH3COOH), labeled at its OH oxygen with the uncommon 18O isotope (shown in red), was treated with aqueousbase, and then the solution was acidified. Two products having the 18Olabel at different locations were formed.Draw the products of attached reaction and indicate stereochemistry aroundstereogenic centers.
