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12c. If you could, please provide an explaination for why the major product would be the SN2 product rather than E2 product?
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- 1. Explain the solubility behavior of the alcohols and phenols in water as a function of: a. Branching in the structure b. Relative proportion of hydrophilic to hydrophobic bonds 2. Based on oxidation test, classify the alcohols and phenols according to the following categories: easily oxidizable, oxidizable, and resistant to oxidation. 3. Explain in 2 – 3 sentences the reactivity differences of the alcohols towards the Lucas reagent. 4. Explain in 2 – 3 sentences the solubility of alcohols and phenols in water.Tunicates are marine animals that are called "sea squirts" because when they are taken out of water, they tend to contract and expel seawater. Lepadiformine is a cytotoxic agent (toxic to cells) isolated from a marine tunicate. During a recent synthesis of lepadiformine, the investigators observed the formation of an interesting by-product (3) while treating diol 1 with a reagent similar in function to PBr3 (J. Org. Chem. 2012, 77, 3390–3400):1.Write the product of 4-chloro-1-hexyne with the following reagents a) ---1.BH3 2.H2o2, - OH---> b) ---2 HBr--> c) ---H2O,H2SO4, HgSO4-->
- Explain how the reaction of (CH3)2CHCH(Cl)CH3 with H2O yields two substitutionproducts, (CH3)2CHCH(OH)CH3 and (CH3)2C(OH)CH2CH32-Methylpropane have more than one kind of hydrogen and will generate 2 different products with bromination in the presence of uv light. t or f3 Organic Chemistry, helppp with ALL PARTS(A&B) Consider the monoterpene linalool, a natural product used in the fragrance industry. When linalool (right panel) is treated with a strong protic acid in the presence of heat, 12 distinct products form. a. Given the initial structure of linalool, draw the structure of these 12 products b. Show the structure of the five intermediates that facilitate the formation of these 12 products and use arrow pushing to show how the intermediates form
- Draw the structure of the major product of 2-methyl-3-heptyne + H2, Lindlar catalyst f.benzene + CH3CH2CH2Cl in AlCl3Wittig reactions with the following -chloroethers can be used for the synthesis of aldehydes and ketones. (a) Draw the structure of the triphenylphosphonium salt and Wittig reagent formed from each chloroether. (b) Draw the structural formula of the product formed by treating each Wittig reagent with cyclopentanone. Note that the functional group is an enol ether or, alternatively, a vinyl ether. (c) Draw the structural formula of the product formed on acid-catalyzed hydrolysis of each enol ether from part (b).Propose a short synthesis f or ONE of the following molecules. You can start with acetylene, and alkyl halides from 1-4 carbons in length. You can also use an reagents you wish. a) Hexan-3-one (CH3CH2COCH2CH2CH3)
- 1. What type of reaction is occuring in step 3? (halogenation, hydrohalogenation, reduction, keto–enol tautomerism, dehydrohalogenation, acid-catalyzed hydration, base-catalyzed hydration) 2. Which reagent is necessary for step 3? (Br2, HBr, H2/Pt, NaNH2, H20/H2SO4/HgSO4)1. Draw the structure of a hydrocarbon that reacts with 2 equivalents of H2 on catalytic hydrogenation and gives only succinic acidic on reaction with acidic KMnO4.Benzene is one of the compounds used as octane enhancers in unleaded gasoline. It is manufactured by thecatalytic conversion of acetylene to benzene: 3C2 H2(g) ⇌ C6 H6(g). Which value of Kc would make this reactionmost useful commercially? Kc ≈ 0.01, Kc ≈ 1, or Kc ≈ 10. Explain your answer
