Caction using 100%. water as the solvent nstead of S%. aqueous acetone?

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 30MP: The carbocation electrophile in a Friede1-Crafts reaction can be generated by an alternate means...
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camparing vanious alkyl halides
reactivity toward SN1 reactions using
water as a nucleopnile
Entry # Alko| halide K(x101min")
0.2231 t 0.0041
Eq(kcsI)
COHS CH 2 C1
Cetts CH2Br
coHs CHCI 2
Ce Hs CHCIBr
Cuts CCI3
CoHs CC12 Br A 212214)
21.2
2.
5684I 0.085
19.1
2.214 E 0.037
23.3
31.08 1 0.19
110.5 0.9
4
21.9
20.5
19.2
reaction was dame in 50%. aqueOUS
acetune at 30°C
reaction
n scherre
fur entry #1
H2O
->
acetane
Transcribed Image Text:camparing vanious alkyl halides reactivity toward SN1 reactions using water as a nucleopnile Entry # Alko| halide K(x101min") 0.2231 t 0.0041 Eq(kcsI) COHS CH 2 C1 Cetts CH2Br coHs CHCI 2 Ce Hs CHCIBr Cuts CCI3 CoHs CC12 Br A 212214) 21.2 2. 5684I 0.085 19.1 2.214 E 0.037 23.3 31.08 1 0.19 110.5 0.9 4 21.9 20.5 19.2 reaction was dame in 50%. aqueOUS acetune at 30°C reaction n scherre fur entry #1 H2O -> acetane
why can the study not perfom the
reaction
using 100%. water as the solvent
instead of S7. aqueous acerone?
Transcribed Image Text:why can the study not perfom the reaction using 100%. water as the solvent instead of S7. aqueous acerone?
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ISBN:
9781305080485
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John E. McMurry
Publisher:
Cengage Learning