The methoxy group is reported as having σpara and σmeta values that differ in sign (σmeta =+0.12; σpara = –0.27). What specific experiments are performed to determine these s values?Explain why the σpara and σmeta values are of different sign and what those signs indicate.
The methoxy group is reported as having σpara and σmeta values that differ in sign (σmeta =+0.12; σpara = –0.27). What specific experiments are performed to determine these s values?Explain why the σpara and σmeta values are of different sign and what those signs indicate.
Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.33P
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Question
The methoxy group is reported as having σpara and σmeta values that differ in sign (σmeta =
+0.12; σpara = –0.27). What specific experiments are performed to determine these s values?
Explain why the σpara and σmeta values are of different sign and what those signs indicate.
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