calculate equilibrium constants for the following reactions. Assume 298.15 K if no temperature is given. H2O (l) <=> H+ (aq) + OH- (aq)

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter17: Electrochemistry
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Problem 99QAP: The standard potential for the reduction of AgSCN is 0.0895 V. AgSCN(s)+eAg(s)+SCN(aq) Find another...
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Use the data from the redox table (appendix L in the text) to calculate equilibrium constants for the following reactions. Assume 298.15 K if no temperature is given.
H2O (l) <=> H+ (aq) + OH- (aq)

TABLE 18.1 Standard Reduction Potentials in Water at 25°C
Potential (V)
Reduction Half-Reaction
F2(g) + 2 e-→ 2F (aq)
MnO, (aq) + 8 H*(aq) + 5 e
Cl2(8) + 2 e 2 CI (aq)
Cr,O,2 (aq) + 14 H*(aq) + 6 e 2 Cr*(aq) + 7 H20(0)
O2(g) + 4 H*(aq) + 4e 2 H2O(1)
Br2(1) + 2 e- 2 Br (aq)
NO3 (aq) + 4 H*(aq) + 3 e NO(g) + 2 H2O(1)
Ag*(aq) + e-
Fe* (aq) + e - Fe2*(aq)
O2(g) + 2 H*(aq) + 2 e H2O2(aq)
MnO, (aq) + 2 H20(1) + 3e - MnO2(s) + 4 OH (aq)
I2(s) + 2 e 21(aq)
O2(g) + 2 H2O(1) + 4e 4 OH (aq)
Cu²"(aq) + 2 e
2H*(aq) + 2 e¯ – H2(g)
Ni2*(aq) + 2 e
Fe2*(aq) + 2 e
Zn2*(aq) + 2 e
+2.87
+1.51
Mn2*(aq) + 4 H20(1)
+1.36
+1.33
+1.23
+1.06
+0.96
+0.80
Ag(s)
+0.77
+0.68
+0.59
+0.54
+0.40
+0.34
Cu(s)
-
0 [defined]
>
-0.28
Ni(s)
Fe(s)
-0.44
-0.76
Zn(s)
2 H2O(1) + 2e
Al3*(aq) + 3 e
Na*(aq) + e - Na(s)
Li*(aq) + e Li(s)
-0.83
H2(g) + 2 OH (aq)
Al(s)
-1.66
-2.71
-3.05
-
Transcribed Image Text:TABLE 18.1 Standard Reduction Potentials in Water at 25°C Potential (V) Reduction Half-Reaction F2(g) + 2 e-→ 2F (aq) MnO, (aq) + 8 H*(aq) + 5 e Cl2(8) + 2 e 2 CI (aq) Cr,O,2 (aq) + 14 H*(aq) + 6 e 2 Cr*(aq) + 7 H20(0) O2(g) + 4 H*(aq) + 4e 2 H2O(1) Br2(1) + 2 e- 2 Br (aq) NO3 (aq) + 4 H*(aq) + 3 e NO(g) + 2 H2O(1) Ag*(aq) + e- Fe* (aq) + e - Fe2*(aq) O2(g) + 2 H*(aq) + 2 e H2O2(aq) MnO, (aq) + 2 H20(1) + 3e - MnO2(s) + 4 OH (aq) I2(s) + 2 e 21(aq) O2(g) + 2 H2O(1) + 4e 4 OH (aq) Cu²"(aq) + 2 e 2H*(aq) + 2 e¯ – H2(g) Ni2*(aq) + 2 e Fe2*(aq) + 2 e Zn2*(aq) + 2 e +2.87 +1.51 Mn2*(aq) + 4 H20(1) +1.36 +1.33 +1.23 +1.06 +0.96 +0.80 Ag(s) +0.77 +0.68 +0.59 +0.54 +0.40 +0.34 Cu(s) - 0 [defined] > -0.28 Ni(s) Fe(s) -0.44 -0.76 Zn(s) 2 H2O(1) + 2e Al3*(aq) + 3 e Na*(aq) + e - Na(s) Li*(aq) + e Li(s) -0.83 H2(g) + 2 OH (aq) Al(s) -1.66 -2.71 -3.05 -
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