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- In determining the amount of copper and the identity of the copper compound in the unknown sample, a 100-mL solution containing 120.8 mg of the sample was initially prepared. Then, 5.00 mL of this solution was pipetted and diluted with deionized water in another 100-mL volumetric flask. The absorbance of this diluted solution was determined three times at the analytical wavelength. The concentration of Cu is 12.678 mg/L, what is the mass of Cu in the analyzed solution and the mass of Cu in the unknown sample?In optical analysis, what are the methods used to calculate the concentration ofa solution from the absorbance measurements of colorimeters?Calculate the molarity of KMnO4 stock solution X used for the analysis. Plot a graph of absorbance A vs. wavelength λ and determine the λ max (maximum wavelength).
- Absorbance measurements were taken on a series of Fe standards complexed with 1,10-phenanthroline. A plot of absorbance vs. concentration yielded a linear curve with the equation y=1.008e03x + 0.0395 (where y is the absorbance and x represents the Fe concentration in moles/L). Using this information calculate the Fe concentration (in ppm) in a 40.0-mL aliquot of ground water that produced an absorbance of 0.580.A water sample has been analyzed for phosphate using UVVS method at 662 nm wavelength. The molar absorptivity of the standard phosphate gives a value of 1.03 x 103 L/mol.cm and an average absorbance reading of 0.431 for the water sample. Is the water from where the sample is taken safe for human drinking?In a pharmaceutical industry a drug Paracetamol (151.163 g/mol) is determined in a sample. A 0.0315 g samples was reacted with methanol and diluted the solution to 1 L. the solution λ max at 243 nm (ε=2.6×104 cm-1 mol-1 L). The solution exhibits an absorbance of 0.642 in a 2 cm cell. Calculate the percentage paracetamol in the sample.
- Given caesium has a body-centred cube with density of 1.93 g/cm3. i. Determine the lattice constant of caesium if the molar mass of caesium is 132.9 g mol-1. (NA = 6.022 x 1023 atom mol-1) ii. Assuming the body-centred caesium is replaced by an anion, X, suggest the type of structure of this derivative. iii. Determine coordination environment for both ions.What is the major limitation of IR regarding the materials that can be used for instrumental components.The absorbance of an iron(III) thiocyanate, Fe(SCN)3 (MM = 230.09 g/mol), solution containing 0.00181 mg/mL is reported as 0.833 at 540 nm. Calculate the specific absortivity of iron(III) thyocyanate with units cm-1 (mg/mL)-1 . A 0.77 cm sample cuvette is used. Report your answer to 3 significant figures.
- Describe the following scanning electron microscopy of powder micrographs of CoIn the figure below we present two curves. The sample to multilayers of graphene. The technician who obtained the spectra does not know how many layers each curve corresponds to. But you do. answer the following: a. With what technique were the spectra obtained?The iron content of a municipal water supply was determined by an atomicabsorption procedure. The absorbance of the water, after a five-fold dilution, was0.755 at 248.3 nm. A standard solution, prepared by dissolving 0.2018 g of pureiron wire in acid, diluting to 250.0 mL, and then making a 100-fold dilution, hadan absorbance of 1.015. Calculate the ppm Fe in the water sample