Calculate the pH of the cathode compartment for the following reaction given Ecell 3.01 V when Cr*+ = 0.12 M, %3D A3+ = 0.32 M, and Cr2O,2- = 0.54 M. 2A1(s) + Cr20,?- (ag) + 14H* (ag) → 2AI** (aq) + 2Cr** (ag) + 7H2O(1) You may need to use the following data: Cr20,2- + 14H+ + 6e + 2Cr+ + 7H2O E =1.33 V Al+ + 3e + Al E = -1.66 V

Fundamentals Of Analytical Chemistry
9th Edition
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Chapter22: Bulk Electrolysis: Electrogravimetry And Coulometry
Section: Chapter Questions
Problem 22.28QAP
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Calculate the pH of the cathode compartment for the following reaction given
Ecell
3.01 V when
Cr*+ = 0.12 M,
%3D
A3+
= 0.32 M, and
Cr2O,2- = 0.54 M.
2A1(s) + Cr20,?- (ag) + 14H* (ag) → 2AI** (aq) + 2Cr** (ag) + 7H2O(1)
You may need to use the following data:
Cr20,2- + 14H+ + 6e + 2Cr+ + 7H2O E =1.33 V
Al+ + 3e + Al
E = -1.66 V
Transcribed Image Text:Calculate the pH of the cathode compartment for the following reaction given Ecell 3.01 V when Cr*+ = 0.12 M, %3D A3+ = 0.32 M, and Cr2O,2- = 0.54 M. 2A1(s) + Cr20,?- (ag) + 14H* (ag) → 2AI** (aq) + 2Cr** (ag) + 7H2O(1) You may need to use the following data: Cr20,2- + 14H+ + 6e + 2Cr+ + 7H2O E =1.33 V Al+ + 3e + Al E = -1.66 V
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