Calculate the emf at 298.15 K generated by the oxidation of Fe2+ by O2 in acidic solution, according to the following reaction: O2(g) + 4H+(aq) + 4Fe2+(aq) ⟶ 4Fe3+(aq) + 2H2O(l) when [H+] = 0.003 M, [Fe3+] = 2.5 x 10 – 4 M, and [Fe2+] = 0.18 M. Also, write the complete (oxidation/reduction) half-reactions.

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter17: Electrochemistry
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Problem 58QAP: Calculate K at 25°C for each of the reactions referred to in Question 32. Assume smallest...
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Calculate the emf at 298.15 K generated by the oxidation of Fe2+ by O2 in acidic solution, according to the following reaction: O2(g) + 4H+(aq) + 4Fe2+(aq) ⟶ 4Fe3+(aq) + 2H2O(l) when [H+] = 0.003 M, [Fe3+] = 2.5 x 10 – 4 M, and [Fe2+] = 0.18 M. Also, write the complete (oxidation/reduction) half-reactions.

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