Calculate the pH of the following solutions. 0.10 M disodium phthalate StructurepK,K.NameNH;CHCH,-O2.20 (СО,Н)9.31 (NH,)6.3 X 10-34.9 x 10-10PhenylalanineCO,H7.11 x 10-36.34 x 10-82.148* 7.198Phosphoric acid*(hydrogen phosphate)НО — Р— Он12.3754.22 X 10-13OH(1.5)6.783 x 10-21.66 x 10-7HP-онPhosphorous acid(hydrogen phosphite)OH1.12 x 10-33.90 x 10-62.950Phthalic acid(benzene-1,2-dicarboxylic acid)5.408cO,HPiperazine(perhydro- 1,4-diazine)5.3339.7314.65 x 10-61.86 X 10-1011.1257.50 x 10-12Piperidine1.12 x 10-22.29 x 10-11-co,H1.952 (СO,Н)10.640 (NH,)Prolinc+H4.8741.34 x 10-5Propanoic acidCH,CH,CO,HH,C=CHCO,H4.2585.52 x 10-5Propenoic acid(аcrylic acid)10.5662.72 x 10-11PropylamineCH;CH,CH,NII;5.206.3,X 10-6Pyridine(azine)Pyridine-2-carboxylic acid(picolinic acid)(1.01) (CO,H)5.39 (NH)9.8 x 10-24.1 x 10-6co,HHO,CPyridine-3-carboxylic acid(nicotinic acid)2.03 (CO,H)4.82 (NH)9.3 x 10-31.51 x 10-sNH+1.4 (POH) (u = 0.1)3.44 (OH) (1p. = 0.1)6.01 (POH) (u = 0.1)8.45 (NH) (u = 0.1)0.043.6 x 10-49.8 x 10-73.5 x 10-90=CHPyridoxal-5-phosphateНо — РОСН,но`CH,H.0.155.5 X 10-31.9 X 10-73.5 X 10-10Pyrophosphoric acid(hydrogen diphosphate)0.832.26(HO),POP(OH),6.729.46*pK, from A. G. Miller and J. W. Macklin, Anal. Chem. 1983, 55, 684.APPENDIX G Acid Dissociation ConstantsАP18

Given, The pH of the solutions. 0.10 M disodium phthalate is:

Answered: Calculate the pH of the following…

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Calculate the pH of the following solutions. 0.10 M disodium phthalate

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter23: Organic Polymers, Natural And Synthetic

Section: Chapter Questions

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Question

Calculate the pH of the following solutions.

0.10 M disodium phthalate

Structure
pK,
K.
Name
NH;
CHCH,-O
2.20 (СО,Н)
9.31 (NH,)
6.3 X 10-3
4.9 x 10-10
Phenylalanine
CO,H
7.11 x 10-3
6.34 x 10-8
2.148
* 7.198
Phosphoric acid*
(hydrogen phosphate)
НО — Р— Он
12.375
4.22 X 10-13
OH
(1.5)
6.78
3 x 10-2
1.66 x 10-7
HP-
он
Phosphorous acid
(hydrogen phosphite)
OH
1.12 x 10-3
3.90 x 10-6
2.950
Phthalic acid
(benzene-1,2-dicarboxylic acid)
5.408
cO,H
Piperazine
(perhydro- 1,4-diazine)
5.333
9.731
4.65 x 10-6
1.86 X 10-10
11.125
7.50 x 10-12
Piperidine
1.12 x 10-2
2.29 x 10-11
-co,H
1.952 (СO,Н)
10.640 (NH,)
Prolinc
+H
4.874
1.34 x 10-5
Propanoic acid
CH,CH,CO,H
H,C=CHCO,H
4.258
5.52 x 10-5
Propenoic acid
(аcrylic acid)
10.566
2.72 x 10-11
Propylamine
CH;CH,CH,NII;
5.20
6.3,X 10-6
Pyridine
(azine)
Pyridine-2-carboxylic acid
(picolinic acid)
(1.01) (CO,H)
5.39 (NH)
9.8 x 10-2
4.1 x 10-6
co,H
HO,C
Pyridine-3-carboxylic acid
(nicotinic acid)
2.03 (CO,H)
4.82 (NH)
9.3 x 10-3
1.51 x 10-s
NH+
1.4 (POH) (u = 0.1)
3.44 (OH) (1p. = 0.1)
6.01 (POH) (u = 0.1)
8.45 (NH) (u = 0.1)
0.04
3.6 x 10-4
9.8 x 10-7
3.5 x 10-9
0=CH
Pyridoxal-5-phosphate
Но — РОСН,
но
`CH,
H.
0.15
5.5 X 10-3
1.9 X 10-7
3.5 X 10-10
Pyrophosphoric acid
(hydrogen diphosphate)
0.83
2.26
(HO),POP(OH),
6.72
9.46
*pK, from A. G. Miller and J. W. Macklin, Anal. Chem. 1983, 55, 684.
APPENDIX G Acid Dissociation Constants
АP18

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