Calculate the potential of a platinum electrode immersed in a solution that is  (a) 0.0613 M in K4Fe(CN)6 and 0.00669 M inK3Fe(CN)6. E0=0.36 (b) 0.0400 M in FeSO4 and 0.00915 M in Fe2(SO4)3. E0=0.771 (c) buffered to a pH of 5.55 and saturated with H2 at 1.00 atm.

Fundamentals Of Analytical Chemistry
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Chapter18: Introduction To Electrochemistry
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Problem 18.14QAP
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  • Calculate the potential of a platinum electrode immersed in a solution that is

 (a) 0.0613 M in K4Fe(CN)6 and 0.00669 M inK3Fe(CN)6. E0=0.36

(b) 0.0400 M in FeSO4 and 0.00915 M in Fe2(SO4)3. E0=0.771

(c) buffered to a pH of 5.55 and saturated with H2 at 1.00 atm.

(d) 0.1015 M in V(OH)4+, 0.0799 M in VO2+, and 0.0800 M in HClO4. E0=1

(e) prepared by mixing 50.00 mL of 0.0607 M Ce(SO4)2 with an equal volume of 0.100 M FeCl2 (assume solutions were 1.00 M in H2SO4 and use formal potentials).E0=0.68

(f ) prepared by mixing 25.00 mL of 0.0832 M V2(SO4)3 with 50.00 mL of 0.00628 M V(OH)4+ and has a pH of 1.00.

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