-Calorimetry Questions 1. A 24.6 g sample of nickel is heated to 110.0 °C and then placed in a coffee-cup calorimeter containing 125 g of water at a temperature of 23.00 °C. After the nickel cools, the final temperature of the metal and water is 24.83 °C. Assuming that no heat has escaped to the surroundings or has been absorbed by the calorimeter, calculate the specific heat of nickel. 2. When solutions of an acid and a base are mixed, heat is released. Using a coffee-cup calorimeter, 100.0 mL of 0.100 mol/L HCI are mixed with 100.0 mL 0.100 mol/L NaOH solution. The initial temperature of the solutions were 22.6 °C, and the temperature after mixing was 32.4 °C. Calculate the molar enthalpy of neutralization for the reaction: HCI (aq) + NaOH (aq) → NaCI (aq) + H,0 (1)

-Calorimetry Questions 1. A 24.6 g sample of nickel is heated to 110.0 °C and then placed in a coffee-cup calorimeter containing 125 g of water at a temperature of 23.00 °C. After the nickel cools, the final temperature of the metal and water is 24.83 °C. Assuming that no heat has escaped to the surroundings or has been absorbed by the calorimeter, calculate the specific heat of nickel. 2. When solutions of an acid and a base are mixed, heat is released. Using a coffee-cup calorimeter, 100.0 mL of 0.100 mol/L HCI are mixed with 100.0 mL 0.100 mol/L NaOH solution. The initial temperature of the solutions were 22.6 °C, and the temperature after mixing was 32.4 °C. Calculate the molar enthalpy of neutralization for the reaction: HCI (aq) + NaOH (aq) → NaCI (aq) + H,0 (1)

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter7: Chemical Energy

Section: Chapter Questions

Problem 109AE: A sample of nickel is heated to 99.8C and placed in a coffee-cup calorimeter containing 150.0 g...

See similar textbooks

Similar questions

9.35 A piece of titanium metal with a mass of 20.8 g is heated in boiling water to 99.5°C and then dropped into a coffee cup calorimeter containing 75.0 g of water at 2 1.7°C. When thermal equilibrium is reached, the final temperature is 24.3°C. Calculate the specific heat capacity of titanium.
A sample of nickel is heated to 99.8C and placed in a coffee-cup calorimeter containing 150.0 g water at 23.5C. After the metal cools, the final temperature of metal and water mixture is 25.0C. If the specific heat capacity of nickel is 0.444 J/C g, what mass of nickel was originally heated? Assume no heat loss to the surroundings.
In earlier times, ethyl ether was commonly used as an anesthetic. It is, however, highly flammable. When five milliliters of ethyl ether, C4H10O(l)(d=0.714g/mL), are burned in a bomb calorimeter, the temperature rises from 23.5C to 39.7C. The calorimeter contains 1.200 kg of water and has a heat capacity of 5.32 kJ/C. (a) What is qH2o? (b) What is qcal? (c) What is q for the combustion of 5.00 mL of ethyl ether? (d) What is q for the combustion of one mole of ethyl ether?
Adding 5.44 g of NH4NO3(s) to 150.0 g of water in a coffee-cup calorimeter (with stirring to dissolve the salt) resulted in a decrease in temperature from 18.6 C to 16.2 C. Calculate the enthalpy change for dissolving NH4NO3(s) in water, in kJ/mol. Assume the solution (whose mass is 155.4 g) has a specific heat capacity of 4.2 J/g K. (Cold packs take advantage of the fact that dissolving ammonium nitrate in water is an endothermic process.)
In a constant-volume calorimeter, 35.0g of H2cools from 75.3C to25.0C. Calculate w, q, U, and H for the process.
Assume 200. mL of 0.400 M HCl is mixed with 200. mL of 0.400 M NaOH in a coffee-cup calorimeter The temperature of the solutions before mixing was 25.10 C; after mixing and allowing the reaction to occur, the temperature is 27.78 C. What is the enthalpy change when one mole of acid is neutralized? (Assume that the densities of all solutions are 1.00 g/mL and their specific heat capacities are 4.20 J/g K.)
In a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each experiment. Since the amount of water is not constant from experiment to experiment, the mass of water must be measured in each case. The heat capacity of the calorimeter is broken down into two parts: the water and the calorimeter components. If a calorimeter contains 1.00 kg water and has a total heat capacity of 10.84 kJ/C, what is the heat capacity of the calorimeter components?
A sample of 0.562 g of carbon is burned in oxygen in a bomb calorimeter, producing carbon dioxide. Assume both the reactants and products are under standard state conditions, and that the heat released is directly proportional to the enthalpy of combustion of graphite. The temperature of the calorimeter increases from 26.74 C to 27.93 C. What is the heat capacity of the calorimeter and its contents?
A student performing a calorimetry experiment combined 100.0 ml. of 0.50 M HCI and 100.0 ml. of 0.50 M NaOH in a StyrofoamTM cup calorimeter. Both solutions were initially at 20.0 C, but when the two were mixed, the temperature rose to 23.2 C (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 ml of 0.50 M NaOH. WIII the AT observed be greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCI and 100.0 ml. of 1.00 M NaOH. Will the T observed be greater than, less than, or equal to that in the first experiment, and why?
When a 0.740-g sample of trinitrotoluene (TNT), C7H5N2O6, is burned in a bomb calorimeter, the temperature increases from 23.4 C to 26.9 C. The heat capacity of the calorimeter is 534 J/C, and it contains 675 mL of water. How much heat was produced by the combustion of the TNT sample?
A balloon expands from 0.75 L to 1.20 L as it is heated under a constant pressure of 1.01 105 Pa. Calculate the work (in J) done by the balloon on the environment.
9.104 An engineer is using sodium metal as a cooling agent in a design because it has useful thermal properties. Looting up the heat capacity, the engineer finds a value of 28.2 J mol-l °C-l. Carelessly, he wrote this number down without units. As a result, it was later taken as specific heat. (a) What would he the difference between these two values? (b) Would the engineer overestimate the ability of sodium to remove heat from the system or underestimate it because of this error? Be sure to explain your reasoning.