Which one of the following is NOT a possible completion of the following reaction? CH,OH но- 1. NABH, HO 2. acidic workup но- H- -OH ČH,OH A. D-talose B. D-tagatose C. the C-3 epimer of D-gulose D. the C-5 epimer of L-psicose E. the C-5 epimer of L-allose F. the C-3 epimer of D-idose G. g. the C-3 epimer of L-glucose O A O B OD

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter25: Biomolecules: Carbohydrates
Section25.SE: Something Extra
Problem 48AP
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Which one of the following is NOT a possible completion of the following reaction?
CH,OH
но
но
1. NABH,
2. acidic workup
но
H-
OH
ČH,OH
A. D-talose
B. D-tagatose
C. the C-3 epimer of D-gulose
D. the C-5 epimer of L-psicose
E. the C-5 epimer of L-allose
F. the C-3 epimer of D-idose
G. g. the C-3 epimer of L-glucose
A
В
E
F
O G
Transcribed Image Text:Which one of the following is NOT a possible completion of the following reaction? CH,OH но но 1. NABH, 2. acidic workup но H- OH ČH,OH A. D-talose B. D-tagatose C. the C-3 epimer of D-gulose D. the C-5 epimer of L-psicose E. the C-5 epimer of L-allose F. the C-3 epimer of D-idose G. g. the C-3 epimer of L-glucose A В E F O G
Which one of the following structures is/are NOT an equilibrium product of base treatment of D-idose?
H.
OH
HO
но.
CH3
но-
H-
он
H-
OH
HO
-H-
H-
он
H-
OH
H-
OH
H-
OH
он
но
H-
но
--
но
но-
H-
он
H-
он
H-
OH
H-
он
OH
ČH,OH
ČH,OH
CH,OH
CH,OH
ČH,OH
а.
b.
с.
d.
е.
a
d
e
Transcribed Image Text:Which one of the following structures is/are NOT an equilibrium product of base treatment of D-idose? H. OH HO но. CH3 но- H- он H- OH HO -H- H- он H- OH H- OH H- OH он но H- но -- но но- H- он H- он H- OH H- он OH ČH,OH ČH,OH CH,OH CH,OH ČH,OH а. b. с. d. е. a d e
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