Question 2 The bromination of a hydrated amine complex in aqueous system was studied. The reaction is: Complex + Br2 (Complex-Br) + Br + H* es m3, while the initial tion is irreversible under The initial bromine concentration was 72.6 micron complex concentration was 1.49 moles m³. The ri these conditions. The following data were reported from the study. Number Time, t Br2 concentration in (seconds) solution (micromole m3) 72.6 432 63.6 684 58.9 936 55.3 1188 51.6 6 1422 48.1 1632 45.2 8 2058 38.8 9. 2442 35.1 (a) In this case, what would be the limiting reactant? Explain your answer. (b) Suggest a rate equation for the reaction studied. Give clear reasoning for your assumptions. 1/2345o7

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question 2
The bromination of a hydrated amine complex in aqueous system was studied.
The reaction is:
Complex + Br2
(Complex-Br) + Br
+ H*
es m3, while the initial
tion is irreversible under
The initial bromine concentration was 72.6 micron
complex concentration was 1.49 moles m³. The ri
these conditions.
The following data were reported from the study.
Number
Time, t
Br2 concentration in
(seconds)
solution (micromole m3)
72.6
432
63.6
684
58.9
936
55.3
1188
51.6
6
1422
48.1
1632
45.2
8
2058
38.8
9.
2442
35.1
(a) In this case, what would be the limiting reactant? Explain your answer.
(b) Suggest a rate equation for the reaction studied. Give clear reasoning for
your assumptions.
1/2345o7
Transcribed Image Text:Question 2 The bromination of a hydrated amine complex in aqueous system was studied. The reaction is: Complex + Br2 (Complex-Br) + Br + H* es m3, while the initial tion is irreversible under The initial bromine concentration was 72.6 micron complex concentration was 1.49 moles m³. The ri these conditions. The following data were reported from the study. Number Time, t Br2 concentration in (seconds) solution (micromole m3) 72.6 432 63.6 684 58.9 936 55.3 1188 51.6 6 1422 48.1 1632 45.2 8 2058 38.8 9. 2442 35.1 (a) In this case, what would be the limiting reactant? Explain your answer. (b) Suggest a rate equation for the reaction studied. Give clear reasoning for your assumptions. 1/2345o7
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