8 Chemical Mechanism8.The mechanism for the reaction described byNO, (g) + CO(g) -→ CO,(g) + NO(g)is suggested to be(1) 2 NO,(g) –→ NO,(g) + NO(g)k2(2) NO,(g) + CO(g)- NO, (g) + CO,g)3) NO219) +Coca) > NOg) + cOz eg)The experimental rate law for the production of [CO2] = ki [NO2]? ord[CO2]k [NO2]?dtd[NO3]Assuming that [NO3] is governed by a steady state (= 0 ), is this a valid mechanism? i.e showdtthat using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the waysd[CO2]that [NO3] and [CO2] are created and destroyed, INO3]= ?dtand= ? )dt

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Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g)→ CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) (3)ON + (3)ON NO, (g) + CO,(g) k2 (2) NO, (g) + CO(g) · 3) NO219) +Coa)7 NOg) +cOzeg) The experimental rate law for the production of [CO2] = k1 [NO2]? or d[CO2] . k[NO2]? %3D dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] , d[Co2] = ? ) dt = ? and that [NO3] and [CO2] are created and destroyed, dt

Chemical Mechanism 8. The mechanism for the reaction described by NO, (g) + CO(g)→ CO,(g) + NO(g) is suggested to be (1) 2 NO,(g) (3)ON + (3)ON NO, (g) + CO,(g) k2 (2) NO, (g) + CO(g) · 3) NO219) +Coa)7 NOg) +cOzeg) The experimental rate law for the production of [CO2] = k1 [NO2]? or d[CO2] . k[NO2]? %3D dt d[NO3] Assuming that [NO3] is governed by a steady state ( = 0 ), is this a valid mechanism? i.e show dt that using elementary reactions 1 and 2, the experimental rate law can found. (Hint write out all the ways d[NO3] , d[Co2] = ? ) dt = ? and that [NO3] and [CO2] are created and destroyed, dt

Chemistry: An Atoms First Approach

2nd Edition

ISBN:9781305079243

Author:Steven S. Zumdahl, Susan A. Zumdahl

Publisher:Steven S. Zumdahl, Susan A. Zumdahl

Chapter11: Chemical Kinetics

Section: Chapter Questions

Problem 80E

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