Chlorine dioxide, CIO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives CI03¯ and ClO2 ions. 2C102 (aq) + 20H (aq) → Cl03-(ag) + ClO, (aq) + H2O(1) To obtain the rate law for this reaction, the following experiments were run and, for each, the initial rate of reaction of CI0, was determined. Initial Concentration Initial Concentration Initial Rate of C102 (mol/L) of OH (mo/L) (mol(L•s)) Exp. 1 3.9 x 10-2 9.6 x 10-2 3.34 × 10-2 Exp. 2 1.3 x 10-2 9.6 x 10-2 3.72 x 10-3 Exp. 3 1.3 x 10-2 0.29 1.12 x 10-2 a Obtain the rate law. (Use k for the rate constant.) Rate law =

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Chapter12: Chemical Kinetics
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Problem 4RQ: The initial rate for a reaction is equal to the slope of the tangent line at t 0 in a plot of [A]...
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Chlorine dioxide, CIO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives ClO3¯ and ClO2 ions.
2C102 (ag) + 20H (ag) → C103- (ag) + CIO2 (aq) + H2O(1)
To obtain the rate law for this reaction, the following experiments were run and, for each, the initial rate of reaction of CIO2 was determined.
Initial Concentration Initial Concentration Initial Rate
of C102 (mol/L)
of OH (mol/L)
(mol/(L-s))
Exp. 1
3.9 x 10-2
9.6 x 10-2
3.34 x 10-2
Exp. 2
1.3 x 10-
9.6 x 10-2
3.72 x 10-3
Exp. 3
1.3 x 10-2
0.29
1.12 x 10-2
a Obtain the rate law.
(Use k for the rate constant.)
Rate law =
Transcribed Image Text:This question has multiple parts. Work all the parts to get the most points. Chlorine dioxide, CIO2, is a reddish-yellow gas that is soluble in water. In basic solution it gives ClO3¯ and ClO2 ions. 2C102 (ag) + 20H (ag) → C103- (ag) + CIO2 (aq) + H2O(1) To obtain the rate law for this reaction, the following experiments were run and, for each, the initial rate of reaction of CIO2 was determined. Initial Concentration Initial Concentration Initial Rate of C102 (mol/L) of OH (mol/L) (mol/(L-s)) Exp. 1 3.9 x 10-2 9.6 x 10-2 3.34 x 10-2 Exp. 2 1.3 x 10- 9.6 x 10-2 3.72 x 10-3 Exp. 3 1.3 x 10-2 0.29 1.12 x 10-2 a Obtain the rate law. (Use k for the rate constant.) Rate law =
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