Co and Ni can be analysed simultaneously by their reaction with 2, 3-quinoxalinedithiol. Molar absorptivity data at the wavelengths are: Co-Complex Ni-Complex Molar Absorptivity.c 510 nm 36400 5520 656 nm 1240 17500 A 0.519 g sample was dissolved and diluted to 50 ml. A 25 ml aliquot was treated to eliminate interferences; after addition of 2, 3-quinoxalinedithiol, the volume was adjusted to 50 ml. this solution had an absorbance of 0.477 at 510 nm and 0.219 at 656 nm in 1.00 cm cell. Calculate the parts per million of Co and Ni in the sample.

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter26: Molecular Absorption Spectrometry
Section: Chapter Questions
Problem 26.5QAP
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Co and Ni can be analysed simultaneously by their reaction with 2, 3-quinoxalinedithiol.
Molar absorptivity data at the wavelengths are:
Co-Complex
Ni-Complex
Molar Absorptivity.c
510 nm
36400
5520
656 nm
1240
17500
A 0.519 g sample was dissolved and diluted to 50 ml. A 25 ml aliquot was treated to
eliminate interferences; after addition of 2, 3-quinoxalinedithiol, the volume was adjusted to
50 ml. this solution had an absorbance of 0.477 at 510 nm and 0.219 at 656 nm in 1.00 cm
cell.
Calculate the parts per million of Co and Ni in the sample.
Transcribed Image Text:Co and Ni can be analysed simultaneously by their reaction with 2, 3-quinoxalinedithiol. Molar absorptivity data at the wavelengths are: Co-Complex Ni-Complex Molar Absorptivity.c 510 nm 36400 5520 656 nm 1240 17500 A 0.519 g sample was dissolved and diluted to 50 ml. A 25 ml aliquot was treated to eliminate interferences; after addition of 2, 3-quinoxalinedithiol, the volume was adjusted to 50 ml. this solution had an absorbance of 0.477 at 510 nm and 0.219 at 656 nm in 1.00 cm cell. Calculate the parts per million of Co and Ni in the sample.
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