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- a) Write out the first 3 steps only(to the tetrahedral intermediate shown) in the 6-step arrow pushing mechanism showing how ethyl propanoate is hydrolyzed in acid to form propanoic acidand ethanol. b) NaOH/H2O also serveto hydrolyze an ester; briefly explain why NaOH/H2Ois generally preferable.When (CH3CH2)3CBr is added to CH3OH at room temperature, the product is(CH3O)C(CH2CH3)3. Propose a mechanism(s) for the reactions leading to theseproducts and use curved arrows to show the movement of electrons.Oxidation of cholesterol converts the alcohol to a ketone. Under acidic or basic oxidationconditions, the C“C double bond migrates to the more stable, conjugated position. BeforeIR and NMR spectroscopy, chemists watched the UV spectrum of the reaction mixture tofollow the oxidation. Describe how the UV spectrum of the conjugated product, cholest-4-en-3-one, differs from that of cholesterol
- Predict the expected product for each reaction and provide IUPAC name for the correct starting material to yield the desired epoxide: 1. Name of compound 2. Answer A, B, C, or DDeduce the structure of each compound from the information given. All unknowns in this problem have molecularformula C8H12.(a) Upon catalytic hydrogenation, unknown W gives cyclooctane. Ozonolysis of W, followed by reduction with dimethylsulfide, gives octanedioic acid, HOOC¬(CH2)6¬COOH. Draw the structure of Wa.) Give an acceptable name for compound C. (b) Draw the organicproducts formed when C is treated with each reagent: [1] H3O+; [2] −OH,H2O; [3] CH3CH2CH2MgBr (excess), then H2O; [4] LiAlH4, then H2O.
- Answer the following: (i) Haloalkanes easily dissolve in organic solvents, why? .. (ii) What is known as a racemic mixture ? Give an example. (iii) Of the two bromoderivatives, C6H5CH(CH3)Br and C6H5CH(C6H5)Br which one is more reactive in SN1 substitution reaction and why?Identify the reagent e, f, g and hPlease help with F-M, the questions Complete the following reactions which form ethers (A and B) and cyclic ethers (C-E) as major products
- Q2. What are the products of the following reactions? Q3. 2-Bromopentane, when treated with alcoholic KOH yields a mixture of three alkenes A, B and C. Identify A, B and C. Which is predominant? Compound A (C7H11Br) is treated with magnesium in ether to give B (C7H11MgBr), which reacts violently with D2O togive 1-methylcyclohexene with a deuterium atom on the methyl group (C). Reaction of B with acetone (CH3COCH3)followed by hydrolysis gives D (C10H18O). Heating D with concentrated H2SO4 gives E (C10H16), which decolorizestwo equivalents of Br2 to give F (C10H16Br4). E undergoes hydrogenation with excess H2 and a Pt catalyst to giveisobutylcyclohexane. Determine the structures of compounds A through F, and show your reasoning throughout3.provide the starting materials needed to synthesize each compound.