Consider an ionic compound, MX,, composed of generic metal M and generic gaseous halogen X. • The enthalpy of formation of MX, is AH; = -763 kJ/mol. • The enthalpy of sublimation of M is AHsub = 169 kJ/mol. • The first, second, and third ionization energies of M are IEj = 619 kJ/mol, IE2 = 1667 kJ/mol, and IE3 = 2525 kJ/mol. • The electron affinity of X is AHEA = -307 kJ/mol. (Refer to the hint). • The bond energy of X, is BE = 181 kJ/mol. %3D Determine the lattice energy of MX,. -3182.5 AHjattice kJ/mol Incorrect

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Chapter16: Thermodynamics: Directionality Of Chemical Reactions
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O Attempt 1
Consider an ionic compound, MX,, composed of generic metal M and generic gaseous halogen X.
Feedback
3'
• The enthalpy of formation of MX, is AH;
= -763 kJ/mol.
1. sublimation of the metal (enthalpy
• The enthalpy of sublimation of M is AHub.
169 kJ/mol.
of sublimation)
• The first, second, and third ionization energies of M are IE1
= 619 kJ/mol, IE2
= 1667 kJ/mol, and IE3
= 2525 kJ/mol.
M(s)
M(g)
AH sub
• The electron affinity of X is AHEA = -307 kJ/mol. (Refer to the hint).
2. dissociation of the halogen
• The bond energy of X, is BE = 181 kJ/mol.
molecule (bond energy)
Determine the lattice energy of MX3.
X,(g) → 3 X(g)
3. ionization of the metal
(ionization energy)
-3182.5
ΔΗatice
kJ/mol
M(g)
M³*(g) + 3e-
Incorrect
4. electron affinity of the halogen
3 X(g) + 3е-
3X-(g)
5. formation of the compound from
its ions
M³+(g) + 3 X-(g) → MX,
The overall reaction is the formation of
one mole of the compound from its
elements in their standard states.
M(s) + X,(g)
MX;(s)
According to Hess's law, the enthalpy
of the overall reaction is equal to the
sum of the enthalpies of the steps.
Transcribed Image Text:O Attempt 1 Consider an ionic compound, MX,, composed of generic metal M and generic gaseous halogen X. Feedback 3' • The enthalpy of formation of MX, is AH; = -763 kJ/mol. 1. sublimation of the metal (enthalpy • The enthalpy of sublimation of M is AHub. 169 kJ/mol. of sublimation) • The first, second, and third ionization energies of M are IE1 = 619 kJ/mol, IE2 = 1667 kJ/mol, and IE3 = 2525 kJ/mol. M(s) M(g) AH sub • The electron affinity of X is AHEA = -307 kJ/mol. (Refer to the hint). 2. dissociation of the halogen • The bond energy of X, is BE = 181 kJ/mol. molecule (bond energy) Determine the lattice energy of MX3. X,(g) → 3 X(g) 3. ionization of the metal (ionization energy) -3182.5 ΔΗatice kJ/mol M(g) M³*(g) + 3e- Incorrect 4. electron affinity of the halogen 3 X(g) + 3е- 3X-(g) 5. formation of the compound from its ions M³+(g) + 3 X-(g) → MX, The overall reaction is the formation of one mole of the compound from its elements in their standard states. M(s) + X,(g) MX;(s) According to Hess's law, the enthalpy of the overall reaction is equal to the sum of the enthalpies of the steps.
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