Consider an ionic compound, MX2MX2, composed of generic metal MM and generic, gaseous halogen XX. The enthalpy of formation of MX2MX2 is Δ?∘f=−923ΔHf∘=−923 kJ/mol. The enthalpy of sublimation of MM is Δ?sub=131ΔHsub=131 kJ/mol. The first and second ionization energies of MM are IE1=755IE1=755 kJ/mol and IE2=1364IE2=1364 kJ/mol. The electron affinity of XX is Δ?EA=−329ΔHEA=−329 kJ/mol. (Refer to the hint). The bond energy of X2X2 is BE=153BE=153 kJ/mol. Determine the lattice energy of MX2MX2. Δ?lattice=ΔHlattice=   kJ/mol

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Chapter8: Electron Configurations And Periodicity
Section: Chapter Questions
Problem 8.119QP: The lattice energy of an ionic solid such as NaCl is the enthalpy change H for the process in which...
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Consider an ionic compound, MX2MX2, composed of generic metal MM and generic, gaseous halogen XX.

  • The enthalpy of formation of MX2MX2 is Δ?∘f=−923ΔHf∘=−923 kJ/mol.

  • The enthalpy of sublimation of MM is Δ?sub=131ΔHsub=131 kJ/mol.

  • The first and second ionization energies of MM are IE1=755IE1=755 kJ/mol and IE2=1364IE2=1364 kJ/mol.

  • The electron affinity of XX is Δ?EA=−329ΔHEA=−329 kJ/mol. (Refer to the hint).

  • The bond energy of X2X2 is BE=153BE=153 kJ/mol.

Determine the lattice energy of MX2MX2.

Δ?lattice=ΔHlattice=
 
kJ/mol
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