Consider the redox reaction Ag*(aq) + Cu(s) ► Ag(s) + Cu²*(aq) Calculate the E'cell and state if the reaction is spontaneous or not. Half-Reaction E' (V) Clg) + 2e 20 (ag) Cr,0, (ag) + 14H" (aq) + 6e 20 "(ag) + 7H,O) MnO,(s) + 4H"(ag) + 2e Mn"(ag) + 2H,O) NO, (ag) + 4H (aq) + 3e NO(g) + 2H,0(I) Ag (ag) +e Fe"tag) +e Cu*(aq) + 2e = Cu(s) AgCis) +e Agis) + CI (ag) so, (aq) + 4H*(aq) + 2e SO,(g) + 2H,O() Cu?t(ag) +e= Cu"(ag) Sn" (ag) + 2e 2H (ag) + 2e Ph*(ag) + 2e Pb(s) +1.36 +1.33 +1.23 +0.96 Agis) Fe"(ag) +0.80 +0.77 +0.34 +0.22 +0.20 +0.15 +0.13 Sa*(ag) Hg) 0.00 -0.13 2e Sns 2e Ni(s) -0.14 N" (ag) PHSO,s) + H"(ag) + 2e Ph(s) + HSO, (ag) Ca"(ag) + 2e Fe"(ag) + 2e Fe(s) Cr*(ag) + 3e Cris) Za**(ag) + 2e = Zn(s) -0.25 -0.31 Cds) -0.40 -0.44 -0.74 -0.76 O -0.46 V and nonspontaneous O +0.46 V and nonspontaneous O -0.46 V and spontaneous O +0.46 V and spontaneous

Chemistry: Matter and Change
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Chapter20: Electrochemistry
Section20.1: Voltaic Cells
Problem 13SSC
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Consider the redox reaction
Ag*(aq) + Cu(s) → Ag(s) + Cu²+(aq)
Calculate the E'cell and state if the reaction is
spontaneous or not.
Half-Reaction
E (V)
+1.36
+1.33
+1.23
+0.96
+0.80
Clg) + 2e 20 (ag)
Cr,0, (ag) + 14H" (aq) + 6e 20 "(ag) + 7H,O)
MnO,(s) + 4H"(ag) + 2e
NO, (ag) + 4H (aq) + 3e
Ag (ag) +e
Fe"tag) +e
Cu*(aq) + 2e = Cu(s)
AgCKs) +e Agis) + CI (ag)
so (aq) + 4H*(ag) + 2e S0,(g) + 2H;O()
Cu*(ag) +e
Sn" (ag) + 2e Sn"(aq)
2H (ag) + 2e
Ph
Mn" (ag) + 2H,O4)
NO(g) + 2H,O)
Agis)
+0.77
+0.34
+0.22
+0.20
Ca*(ag)
+0.15
+0.13
Hg)
Phis)
0.00
+ 20
-0.13
(ag)
Sn" (ag) + 2e Sn(s)
Ni*(ag) + 20 Ni(s)
PHSO8) + H"(ag) + 2e Pb(3) + HSO, (ag)
Ca"(ag) + 20
Fe"(ag) + 20
C"(ag) + 3e
Za*(ag) + 2e
-0.14
-0.25
-0.31
-0.40
Cds)
Fe(s)
Cris)
-0.44
-0.74
Zna)
-0.76
-0.46 V and nonspontaneous
O +0.46 V and nonspontaneous
-0.46 V and spontaneous
O +0.46 V and spontaneous
Transcribed Image Text:Consider the redox reaction Ag*(aq) + Cu(s) → Ag(s) + Cu²+(aq) Calculate the E'cell and state if the reaction is spontaneous or not. Half-Reaction E (V) +1.36 +1.33 +1.23 +0.96 +0.80 Clg) + 2e 20 (ag) Cr,0, (ag) + 14H" (aq) + 6e 20 "(ag) + 7H,O) MnO,(s) + 4H"(ag) + 2e NO, (ag) + 4H (aq) + 3e Ag (ag) +e Fe"tag) +e Cu*(aq) + 2e = Cu(s) AgCKs) +e Agis) + CI (ag) so (aq) + 4H*(ag) + 2e S0,(g) + 2H;O() Cu*(ag) +e Sn" (ag) + 2e Sn"(aq) 2H (ag) + 2e Ph Mn" (ag) + 2H,O4) NO(g) + 2H,O) Agis) +0.77 +0.34 +0.22 +0.20 Ca*(ag) +0.15 +0.13 Hg) Phis) 0.00 + 20 -0.13 (ag) Sn" (ag) + 2e Sn(s) Ni*(ag) + 20 Ni(s) PHSO8) + H"(ag) + 2e Pb(3) + HSO, (ag) Ca"(ag) + 20 Fe"(ag) + 20 C"(ag) + 3e Za*(ag) + 2e -0.14 -0.25 -0.31 -0.40 Cds) Fe(s) Cris) -0.44 -0.74 Zna) -0.76 -0.46 V and nonspontaneous O +0.46 V and nonspontaneous -0.46 V and spontaneous O +0.46 V and spontaneous
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