Consider the titration of 100.0 mL of 0.10 M phosphoric acid with 0.10 M NaOH. a. Determine the pH at the third half-equivalence point by making the typical assumptions. b. Calculate the pH at the third equivalence point. c. Why must the answer to part a be incorrect? Which assumption made in part a is invalid? d. Calculate the pH at the third half-equivalence point.

Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 74QAP: Fifty cm3 of 1.000 M nitrous acid is titrated with 0.850 M NaOH. What is the pH of the solution (a)...
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Consider the titration of 100.0 mL of 0.10 M phosphoric acid
with 0.10 M NaOH.
a. Determine the pH at the third half-equivalence point by
making the typical assumptions.
b. Calculate the pH at the third equivalence point.
c. Why must the answer to part a be incorrect? Which
assumption made in part a is invalid?
d. Calculate the pH at the third half-equivalence point.

Consider the titration of 100.0 mL of 0.10 M phosphoric acid
with 0.10 M NaOH.
a. Determine the pH at the third half-equivalence point by
making the typical assumptions.
b. Calculate the pH at the third equivalence point.
c. Why must the answer to part a be incorrect? Which
assumption made in part a is invalid?
d. Calculate the pH at the third half-equivalence point.

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