Could someone provide a step by step introduction into how to create a complex splitting diagram got the following hydrogen in red. Trying to grasp an understanding for NMR and i am having trouble. Thank you in advance.

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Mass Spectrometry

This process is an instrumental method in which a sample is changed to fast moving positive ions by electron bombardment. The charged particles vary due to their different mass to charge ratio and are estimated with the help of this difference. It is also called mass spectroscopy.