CrO42- can be used as an indicator when Br- is titrated with Ag+. What concentration of CrO42- should be used so that Ag2CrO4(s) just starts to form at the equivalence point? If a concentration of 0.0010 M CrO42- is used instead, at what concentration of Br- will Ag2CrO(s) just start to precipitate? Do you think this is likely to introduce significant error? The Ksp for Ag2CrO4(s) is 1.2x10-12.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter15: Acid-base Equilibria
Section: Chapter Questions
Problem 77E: Potassium hydrogen phthalate, known as KHP (molar mass = 204.22 g/mol), can be obtained in high...
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CrO42- can be used as an indicator when Br- is titrated with Ag+. What concentration of CrO42- should be used so that Ag2CrO4(s) just starts to form at the equivalence point? If a concentration of 0.0010 M CrO42- is used instead, at what concentration of Br- will Ag2CrO(s) just start to precipitate? Do you think this is likely to introduce significant error? The Ksp for Ag2CrO4(s) is 1.2x10-12.

 

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