d) The reaction 2NO, (g) 2NO (g) + 02 (g) has the rate constantk = 0.63 M-'s. i. Determine the order of the reaction in NO2. ii. If the initial concentration of NO2 is 0.050M, determine the concentration of this reactant after 0.50 hours. ii. The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown below: 2NO (g) + Cl, (g) 2NOCI (g) The following data was then obtained. (under conditions of constant [Cl,]) Time Determine if the following mechanism is consistent with the data. Explain your answer. NO (g) + Cl, (g) NOCI, (g) (fast) NOCI, (g) + NO (g) 2NOCI (g) (slow) IONI/I

d) The reaction 2NO, (g) 2NO (g) + 02 (g) has the rate constantk = 0.63 M-'s. i. Determine the order of the reaction in NO2. ii. If the initial concentration of NO2 is 0.050M, determine the concentration of this reactant after 0.50 hours. ii. The NO in the above reaction is used to produce nitrosyl chloride (NOCI) as shown below: 2NO (g) + Cl, (g) 2NOCI (g) The following data was then obtained. (under conditions of constant [Cl,]) Time Determine if the following mechanism is consistent with the data. Explain your answer. NO (g) + Cl, (g) NOCI, (g) (fast) NOCI, (g) + NO (g) 2NOCI (g) (slow) IONI/I

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter11: Chemical Kinetics: Rates Of Reactions

Section: Chapter Questions

Problem 39QRT

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