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A: The explanation is given below:
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A: There are many examples in real life of a factor affecting the rate of a specific reaction.
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A: To find: The definition for Order of a reaction and Activation energy of a reaction
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A: What is the difference between a reaction intermediate and a transition state?
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- 11.41 For a drug to be effective in treating an illness, its levels in the bloodstream must be maintained for a period of time. One way to measure the level of a drug in the body is to measure its rate of appearance in the urine. The rate of excretion of penicillin is first order, with a half-life of about 30 min. If a person receives an injection of 25 mg of penicillin at t = 0, how much penicillin remains in the body after 3 hours?A proposed mechanism for the gas-phase chlorination of methane is Cl2+CH4CH4Cl+ClCH4ClCH3+HClCH3+Cl2CH3Cl+ClCl+CH4CH3+HCl Suppose the first step is the RDS. What is the expected rate law in terms of the original reactants, Cl2 and CH4? How would you determine if this mechanism might be a potentially correct or, for that matter, a potentially incorrect one?At low temperatures, the rate law for the reaction CO(g)+NO2(g)CO2(g)+NO(g)is as follows: rate=(constant)[ NO2 ]2. Which of the following mechanisms is consistent with the rate law? (a) CO+NO2CO2+NO(b) 2NO2N2O4(fast) N2O4+2CO2CO2+2NO(slow) (c) 2NO2NO3+NO(slow) NO3+CONO2+CO2(fast) (d) 2NO22NO+O2(slow) O2+2CO2CO2(fast)
- Some bacteria are resistant to the antibiotic penicillin because they produce penicillinase, an enzyme with a molecular weight of 3104 g/mol that converts penicillin into inactive molecules. Although the kinetics of enzyme-catalyzed reactions can be complex, at low concentrations this reaction can be described by a rate equation that is first order in the catalyst (penicillinase) and that also involves the concentration of penicillin. From the following data: 1.0 L of a solution containing 0.15 g ( 0.15106 g) of penicillinase, determine the order of the reaction with respect to penicillin and the value of the rate constant. [Penicillin] (M) Rate (mol/L/min) 2.0106 1.01010 3.0106 1.51010 4.0106 2.01010When nitrogen dioxide reacts with carbon monoxide, the following reaction occurs. Â NO2(g)+CO(g)NO(g)+CO2(g)The following data are obtained at a certain temperature: (a) What is the order of the reaction with respect to NO2, CO, and overall? (b) Write the rate expression of the reaction. (c) Calculate k for the reaction. (d) When [ NO2 ]=0.421Mand [ CO ]=0.816M, what is the rate of the reaction at the temperature of the experiments?Consider the thermal decomposition of SO2 at 550oC, the time required to decompose half the reactant was 255 seconds at the initial pressure of 290 torr and 212 second at the initial pressure of 360 torr. Find the order of reaction. Hint: Assume ‘pressure’ is equal to the reactant concentration [A].
- if the rate at which O2 appears change [O2]/change t=6.0 x 10-5 Mol s-1 at a partivular instant at what rate is O3, disappearing at the same time - change[O3 ]/change in timeCalcium oxide (CaO), an important ingredient in cement, is produced by decomposing calcium carbonate (CaCO3) at high temperature: CaCO3(s) → CaO(s) + CO2(g) In one particular reaction, 40 g of CaCO3 is heated at 450°C in a 5.0 L vessel. The pressure of CO2 is 0.12 atm after 7.0 minutes. What is the average rate of CO2 production in moles per minute during the 7 minutes? (Enter in mol/min.) If you assume this rate of decomposition remains constant, how many minutes will it take for the entire sample of CaCO3 to decompose?The reform reaction between steam and gaseous methane ( CH4 ) produces "synthesis gas," a mixture of carbon monoxide gas and dihydrogen gas. Synthesis gas is one of the most widely used industrial chemicals, and is the major industrial source of hydrogen. Suppose a chemical engineer studying a new catalyst for the reform reaction finds that 526. liters per second of methane are consumed when the reaction is run at 186.°C and 0.36atm . Calculate the rate at which dihydrogen is being produced. Give your answer in kilograms per second. Be sure your answer has the correct number of significant digits.
- The reform reaction between steam and gaseous methane (CH4) produces "synthesis gas," a mixture of carbon monoxide gas and dihydrogen gas. Synthesis gas is one of the most widely used industrial chemicals, and is the major industrial source of hydrogen. Suppose a chemical engineer studying a new catalyst for the reform reaction finds that 178. liters per second of methane are consumed when the reaction is run at 189.°C and the methane is supplied at 0.51atm. Calculate the rate at which dihydrogen is being produced. Give your answer in kilograms per second. Round your answer to 2 significant digits. =___kg/sBased on the following data for the reaction A --> products, the order of the reaction is , the rate constant is , and the first half life is . Do not input units in your answer. Conc. A, M t, min 0.960 0.0 0.768 1.0 0.549 3.0 0.480 4.0 0.427 5.0 0.384 6.0 0.275 10.0 0.240 12.0 0.214 14.0The decomposition reaction given below: 2 N2O5(g) 4 NO2(g) + 1 O2(g) is carried out in a closed reaction vessel. If the partial pressure of N2O5(g) is decreasing at the rate of 806 torr/min, what is the rate of change of the total pressure in the vessel?Ptot /t = torr/min