D. In a laboratory where NaHS and HCl are the only available reagents, how many mL of 1.00 M HCl should be added to a 50.0 mL solution containing 1.00 mmol of NaHS to give a buffer solution with a pH of 7.022.

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter14: Acids And Bases
Section14.9: Lewis Acids And Bases
Problem 14.26E
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A. Write all the equilibrium reactions with the corresponding equilibrium constant values for a
diprotic acid, H;S in an aqueous solution. Ka, = 9.5 x 10 Kaz =1.3 x 1014
B. Given the following compounds: H;S (34.065); NaHS (56.065); Na,S (78.065), calculate
the pH of a buffer solution (with a usable pH range) prepared by mixing 1.00 g of the acid
and 1.200 g of its conjugate base and diluting to 1.00 L.
c. Calculate the new pH of the buffer solution in (b) if 5.00 mL of 1.07 M HCl were added to
the buffer prepared in (B).
D. In a laboratory where NaHS and HCI are the only available reagents, how many mL of
1.00 M HCl should be added to a 50.0 ml solution containing 1.00 mmol of NaHS to give a
buffer solution with a pH of 7.022.
Transcribed Image Text:A. Write all the equilibrium reactions with the corresponding equilibrium constant values for a diprotic acid, H;S in an aqueous solution. Ka, = 9.5 x 10 Kaz =1.3 x 1014 B. Given the following compounds: H;S (34.065); NaHS (56.065); Na,S (78.065), calculate the pH of a buffer solution (with a usable pH range) prepared by mixing 1.00 g of the acid and 1.200 g of its conjugate base and diluting to 1.00 L. c. Calculate the new pH of the buffer solution in (b) if 5.00 mL of 1.07 M HCl were added to the buffer prepared in (B). D. In a laboratory where NaHS and HCI are the only available reagents, how many mL of 1.00 M HCl should be added to a 50.0 ml solution containing 1.00 mmol of NaHS to give a buffer solution with a pH of 7.022.
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