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- Hexamethylenetetramine as a food additive (E239), when added to food, plays the role of: A) Taste enhancer B) Preservative C) Flavoring D) EmulsifierWhen the conjugate acid of aniline, C6H5NH3+, reacts with the acetate ion, the following reaction takes place: C6H5NH3+(aq)+CH3COO(aq)C6H5NH2(aq)+CH3COOH(aq) If Kafor C6H5NH3+ is 1.35105 and Kafor CH3COOH is 1.86105 , what is K for the reaction?What is the oxidation product of m-methylbenzaldehyde with K2Cr2O7?
- Citronellol ((3R)-3,7-dimethyloct-6-en-1-ol, C10H20O) is an organic fragrance found in the oil extracted from lemon grass. a) Name the two functional groups present in the molecule. b) When a few drops of bromine dissolved in hexane is added to a sample of citronellol the brown colour of the bromine rapidly disappears. i. What type of chemical reaction has occurred? ii. Draw the structure of the product formed. iii. Name the product. c) The product formed when citronellol is heated with a mixture of potassium dichromate and sulfuric acid gives a yellow/orange precipitate when shaken with Brady’s reagent (2,4-dinitrophenylhydrazine). It also shows a positive result with Fehling’s solution. i. What type of chemical reaction has occurred ? ii. What type of functional group is present in the product? d) Explain the type of stereoisomerism which may occur in citronellol.In 1822, Friedrich Wohler produced the component the compound urea, H2N-CO-NH2 in the labratory. Why was the result of this experiement significant in the history of organic chemistry? and What is the equation showing the synthesis of urea from ammonia cyanate?(CH3)2C=CHCH2CH3 and Ozone (o)3 /Zn product?
- Write reactions of 3-aminopropanoic acid with the following reagents: a. CH3I; b. PBr5;SN2 reaction is an example of a nucleophilic substitution reaction. Imagine that 1-iodobutane reacts with 4-methylheptan-1-ol under basic conditions. Draw the structure of the two reactants.What is the structure of C4H6 that can react with NaNH2 and CH3I? What is the product? What reagents are needed to turn this Product into Z-2-pentene?
